Mechanical property and hydrogen permeability of ultrafine-grained Pd–Ag alloy processed by high-pressure torsion

Hideaki Iwaoka, Tatsuya Ide, Makoto Arita, Zenji Horita

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

A process of high-pressure torsion (HPT) was used to produce an ultrafine-grained Pd–Ag alloy, and to improve mechanical property and hydrogen permeability simultaneously. Hardness values of the HPT-processed sample were much higher than those of a cold-rolled sample which is strengthened by dislocation accumulation. Additionally, in contrast to the degradation of hydrogen permeability in the cold-rolled sample due to a high density of dislocations which act as trapping sites of hydrogen atoms, the hydrogen permeability in the HPT-processed sample was improved due to a high density of high-angle grain boundaries which act as a fast diffusion path. The ultrafine-grained structure in the Pd–Ag alloy was retained during permeation testing at 300 °C due to the addition of silver.

Original languageEnglish
Pages (from-to)24176-24182
Number of pages7
JournalInternational Journal of Hydrogen Energy
Volume42
Issue number38
DOIs
Publication statusPublished - Jan 1 2017

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

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