Mechanism of anomalous type electrodeposition of Fe-Ni alloys from sulfate solutions

Hiroaki Nakano, Masayuki Matsuno, Satoshi Oue, Masaaki Yano, Shigeo Kobayashi, Hisaaki Fukushima

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The electrodeposition of Fe-Ni alloys was performed galvanostatically in the sulfate solutions of pH 1-3 at 40°C and the alloy deposition behavior was compared with that of Zn-iron-group metal alloys to investigate their codeposition mechanism. The deposition behavior of Fe-Ni alloy showed a typical feature of the anomalous codeposition, in which electrochemically less noble Fe deposits preferentially under most plating conditions. The anomalous codeposition behavior in Fe-Ni alloy deposition was evidently dependent on the pH buffer capacity of the solutions. This can be explained in terms of the preferential adsorption of FeOH on the deposition sites of more noble Ni due to the extremely smaller dissociation constant of FeOH + than NiOH + in the multistep reduction process of hydrated iron-group metal ions.

Original languageEnglish
Pages (from-to)548-554
Number of pages7
JournalNippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals
Volume69
Issue number7
DOIs
Publication statusPublished - Jul 1 2005

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Electrodeposition
electrodeposition
Sulfates
sulfates
Iron
iron
plating
Plating
Metal ions
metal ions
Buffers
Deposits
buffers
Metals
deposits
dissociation
Adsorption
adsorption
metals

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Mechanics of Materials
  • Metals and Alloys
  • Materials Chemistry

Cite this

Mechanism of anomalous type electrodeposition of Fe-Ni alloys from sulfate solutions. / Nakano, Hiroaki; Matsuno, Masayuki; Oue, Satoshi; Yano, Masaaki; Kobayashi, Shigeo; Fukushima, Hisaaki.

In: Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals, Vol. 69, No. 7, 01.07.2005, p. 548-554.

Research output: Contribution to journalArticle

Nakano, Hiroaki ; Matsuno, Masayuki ; Oue, Satoshi ; Yano, Masaaki ; Kobayashi, Shigeo ; Fukushima, Hisaaki. / Mechanism of anomalous type electrodeposition of Fe-Ni alloys from sulfate solutions. In: Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals. 2005 ; Vol. 69, No. 7. pp. 548-554.
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