Mechanistic investigation of the formation of H2 from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase

Taisuke Tokunaga, Takeshi Yatabe, Takahiro Matsumoto, Tatsuya Ando, Ki Seok Yoon, Seiji Ogo

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Abstract

We report the mechanistic investigation of catalytic H2 evolution from formic acid in water using a formate-bridged dinuclear Ru complex as a formate hydrogen lyase model. The mechanistic study is based on isotope-labeling experiments involving hydrogen isotope exchange reaction.

Original languageEnglish
Pages (from-to)870-876
Number of pages7
JournalScience and Technology of Advanced Materials
Volume18
Issue number1
DOIs
Publication statusPublished - Dec 31 2017

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formic acid
Isotopes
Hydrogen
Formic acid
Labeling
Water
Experiments
formate hydrogenlyase

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

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title = "Mechanistic investigation of the formation of H2 from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase",
abstract = "We report the mechanistic investigation of catalytic H2 evolution from formic acid in water using a formate-bridged dinuclear Ru complex as a formate hydrogen lyase model. The mechanistic study is based on isotope-labeling experiments involving hydrogen isotope exchange reaction.",
author = "Taisuke Tokunaga and Takeshi Yatabe and Takahiro Matsumoto and Tatsuya Ando and Yoon, {Ki Seok} and Seiji Ogo",
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AU - Matsumoto, Takahiro

AU - Ando, Tatsuya

AU - Yoon, Ki Seok

AU - Ogo, Seiji

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