Mechanistic investigation of the formation of H2 from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase

Taisuke Tokunaga, Takeshi Yatabe, Takahiro Matsumoto, Tatsuya Ando, Ki Seok Yoon, Seiji Ogo

Research output: Contribution to journal › Article

1 Citation (Scopus)

Abstract

We report the mechanistic investigation of catalytic H2 evolution from formic acid in water using a formate-bridged dinuclear Ru complex as a formate hydrogen lyase model. The mechanistic study is based on isotope-labeling experiments involving hydrogen isotope exchange reaction.

Original languageEnglish
Pages (from-to)870-876
Number of pages7
JournalScience and Technology of Advanced Materials
Volume18
Issue number1
DOIs
Publication statusPublished - Dec 31 2017

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formic acid
Isotopes
Hydrogen
Formic acid
Labeling
Water
Experiments
formate hydrogenlyase

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

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Mechanistic investigation of the formation of H2 from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase. / Tokunaga, Taisuke; Yatabe, Takeshi; Matsumoto, Takahiro; Ando, Tatsuya; Yoon, Ki Seok; Ogo, Seiji.

In: Science and Technology of Advanced Materials, Vol. 18, No. 1, 31.12.2017, p. 870-876.

Research output: Contribution to journal › Article

Tokunaga, T, Yatabe, T, Matsumoto, T, Ando, T, Yoon, KS & Ogo, S 2017, 'Mechanistic investigation of the formation of H2 from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase', Science and Technology of Advanced Materials, vol. 18, no. 1, pp. 870-876. https://doi.org/10.1080/14686996.2017.1379857
Tokunaga T, Yatabe T, Matsumoto T, Ando T, Yoon KS, Ogo S. Mechanistic investigation of the formation of H2 from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase. Science and Technology of Advanced Materials. 2017 Dec 31;18(1):870-876. https://doi.org/10.1080/14686996.2017.1379857
Tokunaga, Taisuke ; Yatabe, Takeshi ; Matsumoto, Takahiro ; Ando, Tatsuya ; Yoon, Ki Seok ; Ogo, Seiji. / Mechanistic investigation of the formation of H2 from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase. In: Science and Technology of Advanced Materials. 2017 ; Vol. 18, No. 1. pp. 870-876.
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