Mechanistic investigation of the formation of H2 from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase

Taisuke Tokunaga; Takeshi Yatabe; Takahiro Matsumoto; Tatsuya Ando; Ki Seok Yoon; Seiji Ogo

doi:10.1080/14686996.2017.1379857

Mechanistic investigation of the formation of H₂ from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase

Taisuke Tokunaga, Takeshi Yatabe, Takahiro Matsumoto, Tatsuya Ando, Ki Seok Yoon, Seiji Ogo

Research output: Contribution to journal › Article

1 Citation (Scopus)

Abstract

We report the mechanistic investigation of catalytic H₂ evolution from formic acid in water using a formate-bridged dinuclear Ru complex as a formate hydrogen lyase model. The mechanistic study is based on isotope-labeling experiments involving hydrogen isotope exchange reaction.

Original language	English
Pages (from-to)	870-876
Number of pages	7
Journal	Science and Technology of Advanced Materials
Volume	18
Issue number	1
DOIs	https://doi.org/10.1080/14686996.2017.1379857
Publication status	Published - Dec 31 2017

All Science Journal Classification (ASJC) codes

Materials Science(all)

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title = "Mechanistic investigation of the formation of H2 from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase",

abstract = "We report the mechanistic investigation of catalytic H2 evolution from formic acid in water using a formate-bridged dinuclear Ru complex as a formate hydrogen lyase model. The mechanistic study is based on isotope-labeling experiments involving hydrogen isotope exchange reaction.",

author = "Taisuke Tokunaga and Takeshi Yatabe and Takahiro Matsumoto and Tatsuya Ando and Yoon, {Ki Seok} and Seiji Ogo",

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AU - Ando, Tatsuya

AU - Yoon, Ki Seok

AU - Ogo, Seiji

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