Mechanistic investigation of the formation of H2 from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase

Taisuke Tokunaga, Takeshi Yatabe, Takahiro Matsumoto, Tatsuya Ando, Ki Seok Yoon, Seiji Ogo

    Research output: Contribution to journalArticlepeer-review

    1 Citation (Scopus)

    Abstract

    We report the mechanistic investigation of catalytic H2 evolution from formic acid in water using a formate-bridged dinuclear Ru complex as a formate hydrogen lyase model. The mechanistic study is based on isotope-labeling experiments involving hydrogen isotope exchange reaction.

    Original languageEnglish
    Pages (from-to)870-876
    Number of pages7
    JournalScience and Technology of Advanced Materials
    Volume18
    Issue number1
    DOIs
    Publication statusPublished - Dec 31 2017

    All Science Journal Classification (ASJC) codes

    • Materials Science(all)

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