mer-[Fe(pcq)(CN)3]-: A novel cyanide-containing building block and its application to assembling cyanide-bridged trinuclear FeIII2MnII complexes [pcq- = 8-(pyridine-2-carboxamido)quinoline anion]

Zhong Hai Ni, Hui Zhong Kou, Li Fang Zhang, Wei Wei Ni, Yun Bo Jiang, Ai Li Cui, Joan Ribas, Osamu Sato

Research output: Contribution to journalArticle

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Abstract

A new cyanide-containing building block K[Fe(pcq)(CN)3] [1; pcq- = 8-(pyridine-2-carboxamido)quinoline anion] containing a low-spin FeIII center with three cyanide groups in a meridional arrangement has been successfully designed and synthesized. Three cyanide-bridged trinuclear FeIII2MnII complexes, [Fe(pcq)-(CN)3]2[Mn(CH3OH) 2(H2O)2]·2H2O (2), [Fe(pcq)(CN)3]2[Mn(bipy)2]· CH 3OH·2H2O (3), and [Fe(pcq)(CN)3] 2[Mn(phen)2]·CH3OH·2H 2O (4), have been synthesized and structurally characterized. The magnetic susceptibilities of the three heterometallic complexes have been investigated.

Original languageEnglish
Pages (from-to)9631-9633
Number of pages3
JournalInorganic chemistry
Volume44
Issue number26
DOIs
Publication statusPublished - Dec 26 2005

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quinoline
Cyanides
cyanides
assembling
Anions
pyridines
anions
Magnetic susceptibility
methylidyne
magnetic permeability
pyridine

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

mer-[Fe(pcq)(CN)3]- : A novel cyanide-containing building block and its application to assembling cyanide-bridged trinuclear FeIII2MnII complexes [pcq- = 8-(pyridine-2-carboxamido)quinoline anion]. / Ni, Zhong Hai; Kou, Hui Zhong; Zhang, Li Fang; Ni, Wei Wei; Jiang, Yun Bo; Cui, Ai Li; Ribas, Joan; Sato, Osamu.

In: Inorganic chemistry, Vol. 44, No. 26, 26.12.2005, p. 9631-9633.

Research output: Contribution to journalArticle

Ni, Zhong Hai ; Kou, Hui Zhong ; Zhang, Li Fang ; Ni, Wei Wei ; Jiang, Yun Bo ; Cui, Ai Li ; Ribas, Joan ; Sato, Osamu. / mer-[Fe(pcq)(CN)3]- : A novel cyanide-containing building block and its application to assembling cyanide-bridged trinuclear FeIII2MnII complexes [pcq- = 8-(pyridine-2-carboxamido)quinoline anion]. In: Inorganic chemistry. 2005 ; Vol. 44, No. 26. pp. 9631-9633.
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abstract = "A new cyanide-containing building block K[Fe(pcq)(CN)3] [1; pcq- = 8-(pyridine-2-carboxamido)quinoline anion] containing a low-spin FeIII center with three cyanide groups in a meridional arrangement has been successfully designed and synthesized. Three cyanide-bridged trinuclear FeIII2MnII complexes, [Fe(pcq)-(CN)3]2[Mn(CH3OH) 2(H2O)2]·2H2O (2), [Fe(pcq)(CN)3]2[Mn(bipy)2]· CH 3OH·2H2O (3), and [Fe(pcq)(CN)3] 2[Mn(phen)2]·CH3OH·2H 2O (4), have been synthesized and structurally characterized. The magnetic susceptibilities of the three heterometallic complexes have been investigated.",
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AU - Ni, Zhong Hai

AU - Kou, Hui Zhong

AU - Zhang, Li Fang

AU - Ni, Wei Wei

AU - Jiang, Yun Bo

AU - Cui, Ai Li

AU - Ribas, Joan

AU - Sato, Osamu

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