mer-[Fe(pcq)(CN)3]-: A novel cyanide-containing building block and its application to assembling cyanide-bridged trinuclear FeIII2MnII complexes [pcq- = 8-(pyridine-2-carboxamido)quinoline anion]

Zhong Hai Ni, Hui Zhong Kou, Li Fang Zhang, Wei Wei Ni, Yun Bo Jiang, Ai Li Cui, Joan Ribas, Osamu Sato

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66 Citations (Scopus)

Abstract

A new cyanide-containing building block K[Fe(pcq)(CN)3] [1; pcq- = 8-(pyridine-2-carboxamido)quinoline anion] containing a low-spin FeIII center with three cyanide groups in a meridional arrangement has been successfully designed and synthesized. Three cyanide-bridged trinuclear FeIII2MnII complexes, [Fe(pcq)-(CN)3]2[Mn(CH3OH) 2(H2O)2]·2H2O (2), [Fe(pcq)(CN)3]2[Mn(bipy)2]· CH 3OH·2H2O (3), and [Fe(pcq)(CN)3] 2[Mn(phen)2]·CH3OH·2H 2O (4), have been synthesized and structurally characterized. The magnetic susceptibilities of the three heterometallic complexes have been investigated.

Original languageEnglish
Pages (from-to)9631-9633
Number of pages3
JournalInorganic chemistry
Volume44
Issue number26
DOIs
Publication statusPublished - Dec 26 2005

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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