Meso-trifluoromethyl-substituted subporphyrin from ring-splitting reaction of meso-trifluoromethyl-substituted [32]Heptaphyrin(1.1.1.1.1.1.1)

Ryu Sakamoto, Shohei Saito, Soji Shimizu, Yasuhide Inokuma, Naoki Aratani, Atsuhiro Osuka

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

meso-Trifluoromethyl-substituted subporphyrin was obtained through an extrusion reaction from meso-trifluoromethyl-substituted heptaphyrin( 1.1.1.1.1.1.1) upon combined metallation of Cu(II) and B(III) ions. The subporphyrin exhibited the most blue-shifted Soret-like absorption band among those ever prepared.

Original languageEnglish
Pages (from-to)439-441
Number of pages3
JournalChemistry Letters
Volume39
Issue number5
DOIs
Publication statusPublished - May 3 2010
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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