Meta-linkage design of bis-aryldiazonium modifiers for wavelength tuning of near infrared photoluminescence from locally functionalized single-walled carbon nanotubes

Tomohiro Shiraki, Boda Yu, Tomonari Shiraishi, Tamehito Shiga, Tsuyohiko Fujigaya

    Research output: Contribution to journalArticlepeer-review

    5 Citations (Scopus)

    Abstract

    Local chemical functionalization of single-walled carbon nanotubes has been reported to modulate their near infrared photoluminescence (PL), where defect doping creates new emissive sites on the nanotubes. Previously, we reported on proximal defect doping with the use of bis-aryldiazonium salts, which considerably red-shifted nanotube PL (>1200 nm). In this study, we achieved PL modulation with newly designed bis-aryldiazonium modifiers having meta-linked methylene spacers. The spacer length-dependent wavelength shifts were greater than those of our previous para-linkage design.

    Original languageEnglish
    Pages (from-to)791-794
    Number of pages4
    JournalChemistry Letters
    Volume48
    Issue number8
    DOIs
    Publication statusPublished - 2019

    All Science Journal Classification (ASJC) codes

    • Chemistry(all)

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