Metal complexes of an N-confused calix[4]phyrin derivative - The first X-ray structure of an organometallic compound of divalent copper

Hiroyuki Furuta, Tomoya Ishizuka, Atsuhiro Osuka, Yoshiya Uwatoko, Yuichi Ishikawa

Research output: Contribution to journalArticle

68 Citations (Scopus)

Abstract

Rare organometallic complexes can be stabilized by using an N-confused system as a carbon ligand. A stable organocopper(II) compound of N-confused calix[4]phyrin has been characterized by X-ray crystallography (see picture). Complete π conjugation was found not to be a prerequisite for the formation of the metal-carbon bond.

Original languageEnglish
Pages (from-to)2323-2325
Number of pages3
JournalAngewandte Chemie - International Edition
Volume40
Issue number12
DOIs
Publication statusPublished - Jun 18 2001

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Organometallic Compounds
Coordination Complexes
Organometallics
Metal complexes
Copper
Carbon
Derivatives
X rays
X ray crystallography
Metals
Ligands

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Metal complexes of an N-confused calix[4]phyrin derivative - The first X-ray structure of an organometallic compound of divalent copper. / Furuta, Hiroyuki; Ishizuka, Tomoya; Osuka, Atsuhiro; Uwatoko, Yoshiya; Ishikawa, Yuichi.

In: Angewandte Chemie - International Edition, Vol. 40, No. 12, 18.06.2001, p. 2323-2325.

Research output: Contribution to journalArticle

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