Metal complexes of an N-confused calix[4]phyrin derivative - The first X-ray structure of an organometallic compound of divalent copper

Hiroyuki Furuta, Tomoya Ishizuka, Atsuhiro Osuka, Yoshiya Uwatoko, Yuichi Ishikawa

Research output: Contribution to journalArticle

71 Citations (Scopus)

Abstract

Rare organometallic complexes can be stabilized by using an N-confused system as a carbon ligand. A stable organocopper(II) compound of N-confused calix[4]phyrin has been characterized by X-ray crystallography (see picture). Complete π conjugation was found not to be a prerequisite for the formation of the metal-carbon bond.

Original languageEnglish
Pages (from-to)2323-2325
Number of pages3
JournalAngewandte Chemie - International Edition
Volume40
Issue number12
DOIs
Publication statusPublished - Jun 18 2001
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Fingerprint Dive into the research topics of 'Metal complexes of an N-confused calix[4]phyrin derivative - The first X-ray structure of an organometallic compound of divalent copper'. Together they form a unique fingerprint.

  • Cite this