Metal complexes of an N-confused calix[4]phyrin derivative - The first X-ray structure of an organometallic compound of divalent copper

Hiroyuki Furuta; Tomoya Ishizuka; Atsuhiro Osuka; Yoshiya Uwatoko; Yuichi Ishikawa

doi:10.1002/1521-3773(20010618)40:12<2323::AID-ANIE2323>3.0.CO;2-F

Metal complexes of an N-confused calix[4]phyrin derivative - The first X-ray structure of an organometallic compound of divalent copper

Hiroyuki Furuta, Tomoya Ishizuka, Atsuhiro Osuka, Yoshiya Uwatoko, Yuichi Ishikawa

Research output: Contribution to journal › Article › peer-review

83 Citations (Scopus)

Abstract

Rare organometallic complexes can be stabilized by using an N-confused system as a carbon ligand. A stable organocopper(II) compound of N-confused calix[4]phyrin has been characterized by X-ray crystallography (see picture). Complete π conjugation was found not to be a prerequisite for the formation of the metal-carbon bond.

Original language	English
Pages (from-to)	2323-2325
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	12
DOIs	https://doi.org/10.1002/1521-3773(20010618)40:12<2323::AID-ANIE2323>3.0.CO;2-F
Publication status	Published - Jun 18 2001
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/1521-3773(20010618)40:12<2323::AID-ANIE2323>3.0.CO;2-F

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author = "Hiroyuki Furuta and Tomoya Ishizuka and Atsuhiro Osuka and Yoshiya Uwatoko and Yuichi Ishikawa",

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T1 - Metal complexes of an N-confused calix[4]phyrin derivative - The first X-ray structure of an organometallic compound of divalent copper

AU - Furuta, Hiroyuki

AU - Ishizuka, Tomoya

AU - Osuka, Atsuhiro

AU - Uwatoko, Yoshiya

AU - Ishikawa, Yuichi

PY - 2001/6/18

Y1 - 2001/6/18

N2 - Rare organometallic complexes can be stabilized by using an N-confused system as a carbon ligand. A stable organocopper(II) compound of N-confused calix[4]phyrin has been characterized by X-ray crystallography (see picture). Complete π conjugation was found not to be a prerequisite for the formation of the metal-carbon bond.

AB - Rare organometallic complexes can be stabilized by using an N-confused system as a carbon ligand. A stable organocopper(II) compound of N-confused calix[4]phyrin has been characterized by X-ray crystallography (see picture). Complete π conjugation was found not to be a prerequisite for the formation of the metal-carbon bond.

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DO - 10.1002/1521-3773(20010618)40:12<2323::AID-ANIE2323>3.0.CO;2-F

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IS - 12

ER -

Metal complexes of an N-confused calix[4]phyrin derivative - The first X-ray structure of an organometallic compound of divalent copper

Abstract

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