Metal-imprinted microsphere prepared by surface template polymerization with W/O/W emulsions

Kazuya Uezu, Hiroki Nakamura, Masahiro Goto, Fumiyuki Nakashio, Shintaro Furusaki

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

A Zn(II)-imprinted microsphere is prepared by surface template polymerization with W/OAV emulsions. Dioleyl phosphoric acid, which has two long alkyl chains in the hydrophobic moiety, and divinylbenzene were employed as a functional host and a cross-linking agent, respectively. In order to create a spherical imprinted polymer, composition of the external aqueous phase in the W/O/W emulsion is a key factor: the value of the ionic strength to prevent shrinking of emulsions during polymerization and the choice of the water-soluble surfactant for stabilizing the spherical W/O emulsion are important. The metal-imprinted beads exhibit a high selectivity towards target zinc ions over copper ions. The novel preparation technique is very useful for an industrial application because it can easily control the particle size between 10 and 100 μn.

Original languageEnglish
Pages (from-to)262-267
Number of pages6
JournalJOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Volume32
Issue number3
DOIs
Publication statusPublished - Jan 1 1999

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Emulsions
Microspheres
divinyl benzene
Metals
Polymerization
Ions
Emulsion polymerization
Phosphoric acid
Ionic strength
Surface-Active Agents
Industrial applications
Zinc
Copper
Polymers
Surface active agents
Particle size
Water
Chemical analysis

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Metal-imprinted microsphere prepared by surface template polymerization with W/O/W emulsions. / Uezu, Kazuya; Nakamura, Hiroki; Goto, Masahiro; Nakashio, Fumiyuki; Furusaki, Shintaro.

In: JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, Vol. 32, No. 3, 01.01.1999, p. 262-267.

Research output: Contribution to journalArticle

Uezu, Kazuya ; Nakamura, Hiroki ; Goto, Masahiro ; Nakashio, Fumiyuki ; Furusaki, Shintaro. / Metal-imprinted microsphere prepared by surface template polymerization with W/O/W emulsions. In: JOURNAL OF CHEMICAL ENGINEERING OF JAPAN. 1999 ; Vol. 32, No. 3. pp. 262-267.
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