Metal-induced conformational changes in calix[n]arenes can change the exchange interaction between N-O·radicals

Koji Araki, Ryoji Nakamura, Hideyuki Otsuka, Seiji Shinkai

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Abstract

Calix[n]aryl esters 2n (n=4 and 6) bearing two stable N-O·radicals on the lower rim are synthesized: in 26 the exchange interaction (El) changes in response to a metal-induced 1,2,3-alternate-to-cone conformational change but in 24 the metal-induced rotation of the carbonyl groups is not enough to change the El.

Original languageEnglish
Pages (from-to)2121-2122
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number20
DOIs
Publication statusPublished - Dec 1 1995

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All Science Journal Classification (ASJC) codes

  • Molecular Medicine

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