Metal-induced conformational changes in calix[n]arenes can change the exchange interaction between N-O·radicals

Koji Araki; Ryoji Nakamura; Hideyuki Otsuka; Seiji Shinkai

doi:10.1039/C39950002121

Metal-induced conformational changes in calix[n]arenes can change the exchange interaction between N-O·radicals

Koji Araki, Ryoji Nakamura, Hideyuki Otsuka, Seiji Shinkai

Institute for Advanced Study

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

Calix[n]aryl esters 2_n (n=4 and 6) bearing two stable N-O·radicals on the lower rim are synthesized: in 2₆ the exchange interaction (El) changes in response to a metal-induced 1,2,3-alternate-to-cone conformational change but in 2₄ the metal-induced rotation of the carbonyl groups is not enough to change the El.

Original language	English
Pages (from-to)	2121-2122
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	20
DOIs	https://doi.org/10.1039/C39950002121
Publication status	Published - Dec 1 1995

All Science Journal Classification (ASJC) codes

Molecular Medicine

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10.1039/C39950002121

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title = "Metal-induced conformational changes in calix[n]arenes can change the exchange interaction between N-O·radicals",

abstract = "Calix[n]aryl esters 2n (n=4 and 6) bearing two stable N-O·radicals on the lower rim are synthesized: in 26 the exchange interaction (El) changes in response to a metal-induced 1,2,3-alternate-to-cone conformational change but in 24 the metal-induced rotation of the carbonyl groups is not enough to change the El.",

author = "Koji Araki and Ryoji Nakamura and Hideyuki Otsuka and Seiji Shinkai",

year = "1995",

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doi = "10.1039/C39950002121",

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AU - Araki, Koji

AU - Nakamura, Ryoji

AU - Otsuka, Hideyuki

AU - Shinkai, Seiji

PY - 1995/12/1

Y1 - 1995/12/1

N2 - Calix[n]aryl esters 2n (n=4 and 6) bearing two stable N-O·radicals on the lower rim are synthesized: in 26 the exchange interaction (El) changes in response to a metal-induced 1,2,3-alternate-to-cone conformational change but in 24 the metal-induced rotation of the carbonyl groups is not enough to change the El.

AB - Calix[n]aryl esters 2n (n=4 and 6) bearing two stable N-O·radicals on the lower rim are synthesized: in 26 the exchange interaction (El) changes in response to a metal-induced 1,2,3-alternate-to-cone conformational change but in 24 the metal-induced rotation of the carbonyl groups is not enough to change the El.

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