TY - JOUR
T1 - Metal-organic Framework of [Cu2(BIPA-TC)(DMA)2]n
T2 - A Promising Anode Material for Lithium-Ion Battery
AU - Luo, Yulin
AU - Wu, Mengke
AU - Pang, Baocheng
AU - Ge, Jiawen
AU - Li, Rui
AU - Zhang, Pan
AU - Zhou, Mingjiong
AU - Han, Lei
AU - Okada, Shigeto
N1 - Funding Information:
. This work was financially supported by the National Natural Science Foundation of China (21606135), the Science Technology Department of Zhejiang Province (2017 C31086), the Science Technology Innovation Research Program of Ningbo (2019B10113). This work was also sponsored by K.C. Wong Magna Fund in Ningbo University
Publisher Copyright:
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2020/4/16
Y1 - 2020/4/16
N2 - A copper-based redox-active metal-organic framework (Cu–MOF) is solvothermally synthesized from Cu(NO3)2 with the ligand 5,5-(1,3,6,8-tetraoxobenzo[Imn][3,8]phenanthroline-2-7diyl)-bis-1,3-benzenedicarboxylic acid. The as-prepared Cu–MOF is characterized by X-ray diffraction, automatic sphere surface analyzer, field emission scanning electron microscopy, and X-ray photoelectron spectroscopy. The electrochemical properties of Cu–MOF as an anode are investigated for lithium-ion batteries. The Cu–MOF exhibits superior performance including high reversible capacity and excellent cyclic stability. The Cu–MOF shows high initial charge capacity of 753.7 mAh g−1, and still remains approximately 53% of its capacity after 500 cycles. In addition, it is revealed that the oxidation/reduction of copper ion in Cu–MOF occurred during charge and discharge process.
AB - A copper-based redox-active metal-organic framework (Cu–MOF) is solvothermally synthesized from Cu(NO3)2 with the ligand 5,5-(1,3,6,8-tetraoxobenzo[Imn][3,8]phenanthroline-2-7diyl)-bis-1,3-benzenedicarboxylic acid. The as-prepared Cu–MOF is characterized by X-ray diffraction, automatic sphere surface analyzer, field emission scanning electron microscopy, and X-ray photoelectron spectroscopy. The electrochemical properties of Cu–MOF as an anode are investigated for lithium-ion batteries. The Cu–MOF exhibits superior performance including high reversible capacity and excellent cyclic stability. The Cu–MOF shows high initial charge capacity of 753.7 mAh g−1, and still remains approximately 53% of its capacity after 500 cycles. In addition, it is revealed that the oxidation/reduction of copper ion in Cu–MOF occurred during charge and discharge process.
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U2 - 10.1002/slct.202000503
DO - 10.1002/slct.202000503
M3 - Article
AN - SCOPUS:85091025424
SN - 2365-6549
VL - 5
SP - 4160
EP - 4164
JO - ChemistrySelect
JF - ChemistrySelect
IS - 14
ER -
