Abstract
We have developed a new preparation method (ME method) of supported metal catalysts by using microemulsion. The metal particles in the catalyst prepared by this method were interacted strongly with support and were considered to be positively charged, and the SiO2-supported Rh and Fe catalysts prepared by this method exhibited a unique activity and a good selectivity to oxygenates in the hydrogenation of CO. The Al2O 3-supported Ni catalyst also exhibited an excellent activity and a strong resistance to carbon deposition in the methane-steam reforming. In this review, these interesting catalytic behaviors of the catalysts prepared by ME method were elucidated from the view-point of the electronic state of metals.
| Original language | English |
|---|---|
| Pages (from-to) | 9-17 |
| Number of pages | 9 |
| Journal | Catalysis Surveys from Asia |
| Volume | 6 |
| Issue number | 1-2 |
| Publication status | Published - Dec 1 2002 |
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All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)
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Metal-support interaction and catalysis of the catalysts prepared using microemulsion. / Hayashi, Hiroki; Kishida, Masahiro; Wakabayashi, Katsuhiko.
In: Catalysis Surveys from Asia, Vol. 6, No. 1-2, 01.12.2002, p. 9-17.Research output: Contribution to journal › Review article
}
TY - JOUR
T1 - Metal-support interaction and catalysis of the catalysts prepared using microemulsion
AU - Hayashi, Hiroki
AU - Kishida, Masahiro
AU - Wakabayashi, Katsuhiko
PY - 2002/12/1
Y1 - 2002/12/1
N2 - We have developed a new preparation method (ME method) of supported metal catalysts by using microemulsion. The metal particles in the catalyst prepared by this method were interacted strongly with support and were considered to be positively charged, and the SiO2-supported Rh and Fe catalysts prepared by this method exhibited a unique activity and a good selectivity to oxygenates in the hydrogenation of CO. The Al2O 3-supported Ni catalyst also exhibited an excellent activity and a strong resistance to carbon deposition in the methane-steam reforming. In this review, these interesting catalytic behaviors of the catalysts prepared by ME method were elucidated from the view-point of the electronic state of metals.
AB - We have developed a new preparation method (ME method) of supported metal catalysts by using microemulsion. The metal particles in the catalyst prepared by this method were interacted strongly with support and were considered to be positively charged, and the SiO2-supported Rh and Fe catalysts prepared by this method exhibited a unique activity and a good selectivity to oxygenates in the hydrogenation of CO. The Al2O 3-supported Ni catalyst also exhibited an excellent activity and a strong resistance to carbon deposition in the methane-steam reforming. In this review, these interesting catalytic behaviors of the catalysts prepared by ME method were elucidated from the view-point of the electronic state of metals.
UR - http://www.scopus.com/inward/record.url?scp=0141728502&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0141728502&partnerID=8YFLogxK
M3 - Review article
VL - 6
SP - 9
EP - 17
JO - Catalysis Surveys from Asia
JF - Catalysis Surveys from Asia
SN - 1571-1013
IS - 1-2
ER -