Meta/para-selectivity variation by sulfide/sulfoxide conversion of 6-substituted β-cyclodextrin. Hydrolyses of nitrophenyl acetates. ag

Kahee Fujita, Seiji Ejima, Tadashi Ueda, Taiji Imoto, Hans Rolf Schulten

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Hydrolyses of m- and p-nitrophenyl acetates by 6-deoxy-6-alkylthio-β-cyclodextrins and the corresponding sulfoxides were studied to show that the small chemical conversion from the sulfides to the sulfoxides led to a change of meta/para-selectivity in the hydrolysis of the β-cyclodextrin moiety.

Original languageEnglish
Pages (from-to)3711-3714
Number of pages4
JournalTetrahedron Letters
Volume25
Issue number34
DOIs
Publication statusPublished - 1984

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sulfoxide
Sulfoxides
Cyclodextrins
Sulfides
Hydrolysis
Acetates

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Meta/para-selectivity variation by sulfide/sulfoxide conversion of 6-substituted β-cyclodextrin. Hydrolyses of nitrophenyl acetates. ag. / Fujita, Kahee; Ejima, Seiji; Ueda, Tadashi; Imoto, Taiji; Schulten, Hans Rolf.

In: Tetrahedron Letters, Vol. 25, No. 34, 1984, p. 3711-3714.

Research output: Contribution to journalArticle

Fujita, Kahee ; Ejima, Seiji ; Ueda, Tadashi ; Imoto, Taiji ; Schulten, Hans Rolf. / Meta/para-selectivity variation by sulfide/sulfoxide conversion of 6-substituted β-cyclodextrin. Hydrolyses of nitrophenyl acetates. ag. In: Tetrahedron Letters. 1984 ; Vol. 25, No. 34. pp. 3711-3714.
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