Metathesis reaction of hydrocarbyl ligands across the triruthenium plane

Atsushi Tahara; Mana Kajigaya; Makoto Moriya; Toshiro Takao; Hiroharu Suzuki

doi:10.1002/anie.201002235

Metathesis reaction of hydrocarbyl ligands across the triruthenium plane

Atsushi Tahara, Mana Kajigaya, Makoto Moriya, Toshiro Takao, Hiroharu Suzuki

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Trains and boats and planes: The thermolysis of a tri ruthenium complex having H₃-pentylidyne and μ₃-pentyne ligands on each face of the tri metallic plane exclusively afforded the μ₃- ethylidyne-nroctyne complex. In this reaction, a C₃ fragment migrated from one face of the Ru₃ planeto the other. This corresponds to the selective redistribution of two C₅ molecules into C₂ and C₈ molecules. (Figure Presented)

Original language	English
Pages (from-to)	5898-5901
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	34
DOIs	https://doi.org/10.1002/anie.201002235
Publication status	Published - Aug 9 2010
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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abstract = "Trains and boats and planes: The thermolysis of a tri ruthenium complex having H3-pentylidyne and μ3-pentyne ligands on each face of the tri metallic plane exclusively afforded the μ3- ethylidyne-nroctyne complex. In this reaction, a C3 fragment migrated from one face of the Ru3 planeto the other. This corresponds to the selective redistribution of two C5 molecules into C2 and C8 molecules. (Figure Presented)",

author = "Atsushi Tahara and Mana Kajigaya and Makoto Moriya and Toshiro Takao and Hiroharu Suzuki",

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AU - Tahara, Atsushi

AU - Kajigaya, Mana

AU - Moriya, Makoto

AU - Takao, Toshiro

AU - Suzuki, Hiroharu

PY - 2010/8/9

Y1 - 2010/8/9

N2 - Trains and boats and planes: The thermolysis of a tri ruthenium complex having H3-pentylidyne and μ3-pentyne ligands on each face of the tri metallic plane exclusively afforded the μ3- ethylidyne-nroctyne complex. In this reaction, a C3 fragment migrated from one face of the Ru3 planeto the other. This corresponds to the selective redistribution of two C5 molecules into C2 and C8 molecules. (Figure Presented)

AB - Trains and boats and planes: The thermolysis of a tri ruthenium complex having H3-pentylidyne and μ3-pentyne ligands on each face of the tri metallic plane exclusively afforded the μ3- ethylidyne-nroctyne complex. In this reaction, a C3 fragment migrated from one face of the Ru3 planeto the other. This corresponds to the selective redistribution of two C5 molecules into C2 and C8 molecules. (Figure Presented)

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Metathesis reaction of hydrocarbyl ligands across the triruthenium plane

Abstract

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