Metathesis reaction of hydrocarbyl ligands across the triruthenium plane

Atsushi Tahara, Mana Kajigaya, Makoto Moriya, Toshiro Takao, Hiroharu Suzuki

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Trains and boats and planes: The thermolysis of a tri ruthenium complex having H3-pentylidyne and μ3-pentyne ligands on each face of the tri metallic plane exclusively afforded the μ3- ethylidyne-nroctyne complex. In this reaction, a C3 fragment migrated from one face of the Ru3 planeto the other. This corresponds to the selective redistribution of two C5 molecules into C2 and C8 molecules. (Figure Presented)

Original languageEnglish
Pages (from-to)5898-5901
Number of pages4
JournalAngewandte Chemie - International Edition
Volume49
Issue number34
DOIs
Publication statusPublished - Aug 9 2010
Externally publishedYes

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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