Extremely high concentrations (>1020 cm-3) of active oxygenic radicals, O- and O2-, have been created in the zeolitic crystal, 12CaO·7Al2O3 (C12A7), which can accommodate anions in its cavities. An increase in oxygen pressure and a decrease in water vapor pressure at high temperature enhance the formation of the radicals. The oxidation of Pt is observed on the surface of the material as a result of reaction with the active oxygens.
|Number of pages||2|
|Journal||Journal of the American Chemical Society|
|Publication status||Published - Feb 6 2002|
All Science Journal Classification (ASJC) codes
- Colloid and Surface Chemistry