Microporous layer coated gas diffusion layers for enhanced performance of polymer electrolyte fuel cells

Research output: Contribution to journalArticle

101 Citations (Scopus)

Abstract

The influence of microporous layer (MPL) design parameters for gas diffusion layers (GDLs) on the performance of polymer electrolyte fuel cells (PEFCs) was clarified. Appropriate MPL design parameters vary depending on the humidification of the supplied gas. Under low humidification, decreasing both the MPL pore diameter and the content of polytetrafluoroethylene (PTFE) in the MPL is effective to prevent drying-up of the membrane electrode assembly (MEA) and enhance PEFC performance. Increasing the MPL thickness is also effective for maintaining the humidity of the MEA. However, when the MPL thickness becomes too large, oxygen transport to the electrode through the MPL is reduced, which lowers PEFC performance. Under high humidification, decreasing the MPL mean flow pore diameter to 3 μm is effective for the prevention of flooding and enhancement of PEFC performance. However, when the pore diameter becomes too small, the PEFC performance tends to decrease. Both reduction of the MPL thickness penetrated into the substrate and increase in the PTFE content to 20 mass% enhance the ability of the MPL to prevent flooding.

Original languageEnglish
Pages (from-to)2202-2211
Number of pages10
JournalJournal of Power Sources
Volume195
Issue number8
DOIs
Publication statusPublished - Apr 15 2010

Fingerprint

gaseous diffusion
Diffusion in gases
Electrolytes
fuel cells
Fuel cells
Polymers
electrolytes
polymers
Polytetrafluoroethylene
Polytetrafluoroethylenes
Electrodes
Membranes
polytetrafluoroethylene
porosity
Atmospheric humidity
Drying
electrodes
Gases
assembly
Oxygen

All Science Journal Classification (ASJC) codes

  • Electrical and Electronic Engineering
  • Energy Engineering and Power Technology
  • Renewable Energy, Sustainability and the Environment
  • Physical and Theoretical Chemistry

Cite this

Microporous layer coated gas diffusion layers for enhanced performance of polymer electrolyte fuel cells. / Kitahara, Tatsumi; Konomi, Toshiaki; Nakajima, Hironori.

In: Journal of Power Sources, Vol. 195, No. 8, 15.04.2010, p. 2202-2211.

Research output: Contribution to journalArticle

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