Microstructural studies of core/rim structure of polycarbosilane-derived SiC consolidated by spark plasma sintering

Ji Hwoan Lee, Yoonjoo Lee, Young Hwan Han, Dong Guen Shin, Sukyoung Kim, Byungkoog Jang

Research output: Contribution to journalArticle

Abstract

Recently, attempts have been made to use silicon carbide (SiC) ceramics as a fuel compact in nuclear reactors. However, the use of sintering additives in the conventional sintering of SiC leads to a coarse microstructure with high porosity and large grains due to the low sinterability and the large amount of grain boundaries or a second phase, deteriorating the mechanical properties, and hence limiting widespread industrial applications. In this study, polycarbosilane (PCS) and spark plasma sintering (SPS) as the SiC precursor and sintering method, respectively, were applied to overcome the low sinterability and the use of sintering additives. As the raw material, amorphous PCS was prepared by pyrolysis at 1000 °C. To decrease the particle size, pyrolyzed PCS powder was subjected to ball milling by using high-energy ball milling. The ball-milled amorphous PCS powder was sintered by SPS. Sintering was carried out at different temperatures (i.e., 1700, 1800, and 1900 °C) and pressures (i.e., 40 and 80 MPa). After SPS, the core/rim structure of the sintered pellet was formed on account of the oxygen originating from the native oxide layer and free carbon in the PCS powder as the raw materials. In the core/rim structure comprising the core, as well as the intermediate and rim regions, the microstructure and chemistry of each region exhibited marginal difference with respect to the free carbon and oxygen. The phase fraction of α-SiC increased from the rim region to core region due to the discrepancy of actual loaded pressure on account of friction with the wall surface. The existing carbon was verified to be graphitized carbon. Owing to the short reaction time, graphitization did not completely proceed, and deficient graphitization led to graphitized carbon as not graphite. The introduced oxygen changed to amorphous SiO 2 , which was applied to the sintering-additive-like liquid-phase sintering.

Original languageEnglish
Pages (from-to)12406-12410
Number of pages5
JournalCeramics International
Volume45
Issue number9
DOIs
Publication statusPublished - Jun 15 2019

Fingerprint

Spark plasma sintering
Silicon carbide
Sintering
Carbon
Powders
Graphitization
Ball milling
Oxygen
Raw materials
Liquid phase sintering
Microstructure
Graphite
Nuclear reactors
Oxides
Industrial applications
silicon carbide
Grain boundaries
Pyrolysis
Porosity
Particle size

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Process Chemistry and Technology
  • Surfaces, Coatings and Films
  • Materials Chemistry

Cite this

Microstructural studies of core/rim structure of polycarbosilane-derived SiC consolidated by spark plasma sintering. / Lee, Ji Hwoan; Lee, Yoonjoo; Han, Young Hwan; Shin, Dong Guen; Kim, Sukyoung; Jang, Byungkoog.

In: Ceramics International, Vol. 45, No. 9, 15.06.2019, p. 12406-12410.

Research output: Contribution to journalArticle

Lee, Ji Hwoan ; Lee, Yoonjoo ; Han, Young Hwan ; Shin, Dong Guen ; Kim, Sukyoung ; Jang, Byungkoog. / Microstructural studies of core/rim structure of polycarbosilane-derived SiC consolidated by spark plasma sintering. In: Ceramics International. 2019 ; Vol. 45, No. 9. pp. 12406-12410.
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