Microwave-assisted hydrolysis of biomass over activated carbon supported polyoxometalates

S. Tsubaki; K. Oono; A. Onda; T. Ueda; T. Mitani; M. Hiraoka

doi:10.1039/c6ra28778f

Microwave-assisted hydrolysis of biomass over activated carbon supported polyoxometalates

S. Tsubaki, K. Oono, A. Onda, T. Ueda, T. Mitani, M. Hiraoka

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Activated carbon supported polyoxometalates (AC-POMs) were used for acceleration of hydrolysis of biomass under microwave irradiation. Microwaves exhibited a higher saccharification rate for cellobiose and green seaweed (Monostroma latissimum) over AC-POMs than conductive heating by 1.25 to 1.55-fold. The activity of the AC-POMs was positively correlated with the dielectric loss of the catalysts, suggesting that microwave susceptibility of AC-POMs is relevant to the enhancement of catalysis under microwave irradiation.

Original language	English
Pages (from-to)	12346-12350
Number of pages	5
Journal	RSC Advances
Volume	7
Issue number	20
DOIs	https://doi.org/10.1039/c6ra28778f
Publication status	Published - 2017
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)

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10.1039/c6ra28778f

Cite this

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title = "Microwave-assisted hydrolysis of biomass over activated carbon supported polyoxometalates",

abstract = "Activated carbon supported polyoxometalates (AC-POMs) were used for acceleration of hydrolysis of biomass under microwave irradiation. Microwaves exhibited a higher saccharification rate for cellobiose and green seaweed (Monostroma latissimum) over AC-POMs than conductive heating by 1.25 to 1.55-fold. The activity of the AC-POMs was positively correlated with the dielectric loss of the catalysts, suggesting that microwave susceptibility of AC-POMs is relevant to the enhancement of catalysis under microwave irradiation.",

author = "S. Tsubaki and K. Oono and A. Onda and T. Ueda and T. Mitani and M. Hiraoka",

note = "Funding Information: This study was supported by the Adaptable and Seamless Technology Transfer Program (A-STEP) through Target-driven R&D (Exploratory Research), Japan Science and Technology Agency (AS242Z03337N), Grant-in-Aid for Young Scientists B Japan Society for the Promotion of Science (15K18814) and the Japan Prize Foundation. The dielectric measurements were conducted through Analysis and Development System for Advanced Materials (ADAM) at the Research Institute for Sustainable Humanosphere, Kyoto University. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c6ra28778f",

language = "English",

volume = "7",

pages = "12346--12350",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Microwave-assisted hydrolysis of biomass over activated carbon supported polyoxometalates

AU - Tsubaki, S.

AU - Oono, K.

AU - Onda, A.

AU - Ueda, T.

AU - Mitani, T.

AU - Hiraoka, M.

N1 - Funding Information: This study was supported by the Adaptable and Seamless Technology Transfer Program (A-STEP) through Target-driven R&D (Exploratory Research), Japan Science and Technology Agency (AS242Z03337N), Grant-in-Aid for Young Scientists B Japan Society for the Promotion of Science (15K18814) and the Japan Prize Foundation. The dielectric measurements were conducted through Analysis and Development System for Advanced Materials (ADAM) at the Research Institute for Sustainable Humanosphere, Kyoto University. Publisher Copyright: © The Royal Society of Chemistry.

PY - 2017

Y1 - 2017

N2 - Activated carbon supported polyoxometalates (AC-POMs) were used for acceleration of hydrolysis of biomass under microwave irradiation. Microwaves exhibited a higher saccharification rate for cellobiose and green seaweed (Monostroma latissimum) over AC-POMs than conductive heating by 1.25 to 1.55-fold. The activity of the AC-POMs was positively correlated with the dielectric loss of the catalysts, suggesting that microwave susceptibility of AC-POMs is relevant to the enhancement of catalysis under microwave irradiation.

AB - Activated carbon supported polyoxometalates (AC-POMs) were used for acceleration of hydrolysis of biomass under microwave irradiation. Microwaves exhibited a higher saccharification rate for cellobiose and green seaweed (Monostroma latissimum) over AC-POMs than conductive heating by 1.25 to 1.55-fold. The activity of the AC-POMs was positively correlated with the dielectric loss of the catalysts, suggesting that microwave susceptibility of AC-POMs is relevant to the enhancement of catalysis under microwave irradiation.

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DO - 10.1039/c6ra28778f

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JO - RSC Advances

JF - RSC Advances

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ER -

Microwave-assisted hydrolysis of biomass over activated carbon supported polyoxometalates

Abstract

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