Miscibility in binary mixtures of surfactants

Research output: Chapter in Book/Report/Conference proceedingChapter

3 Citations (Scopus)

Abstract

The miscibility in binary mixtures of surfactants in the organized assemblies at the interface and in the solution is summarized on the basis of the phase diagrams of adsorption, micelle formation, and vesicle formation. In Section II, the thermodynamic equations to obtain the phase diagrams are given for some combinations of binary surfactant systems. Furthermore the criterion of an ideal mixing is proposed. In Section III, the miscibility in the adsorbed film and micelle is demonstrated for some representative systems by using the phase diagrams and the excess Gibbs free energy. In Section IV, the vesicle-micelle transition in the aqueous mixture and the phase transition in the adsorbed films at the oil/water interface are shown and examined from the viewpoint of the miscibility of the surfactants.

Original languageEnglish
Title of host publicationMixed Surfactant Systems, Second Edition, Revised and Expanded
PublisherCRC Press
Pages1-57
Number of pages57
ISBN (Electronic)9781420031010
ISBN (Print)9780824721503
DOIs
Publication statusPublished - Jan 1 2004

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Micelles
Binary mixtures
Surface-Active Agents
Phase diagrams
Solubility
Gibbs free energy
Oils
Phase transitions
Thermodynamics
Adsorption
Water

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Aratono, M., & Takiue, T. (2004). Miscibility in binary mixtures of surfactants. In Mixed Surfactant Systems, Second Edition, Revised and Expanded (pp. 1-57). CRC Press. https://doi.org/10.1201/9781420031010

Miscibility in binary mixtures of surfactants. / Aratono, Makoto; Takiue, Takanori.

Mixed Surfactant Systems, Second Edition, Revised and Expanded. CRC Press, 2004. p. 1-57.

Research output: Chapter in Book/Report/Conference proceedingChapter

Aratono, M & Takiue, T 2004, Miscibility in binary mixtures of surfactants. in Mixed Surfactant Systems, Second Edition, Revised and Expanded. CRC Press, pp. 1-57. https://doi.org/10.1201/9781420031010
Aratono M, Takiue T. Miscibility in binary mixtures of surfactants. In Mixed Surfactant Systems, Second Edition, Revised and Expanded. CRC Press. 2004. p. 1-57 https://doi.org/10.1201/9781420031010
Aratono, Makoto ; Takiue, Takanori. / Miscibility in binary mixtures of surfactants. Mixed Surfactant Systems, Second Edition, Revised and Expanded. CRC Press, 2004. pp. 1-57
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