Mixed conductivity and oxygen permeability of doped Pr 2 NiO 4 -based oxides

Shogo Miyoshi, Tetsuro Furuno, Oravan Sangoanruang, Hiroshige Matsumoto, Tatsumi Ishihara

Research output: Contribution to journalArticle

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Abstract

Pr2 NiO4 -based oxides were studied as a series of new mixed electronic and oxide-ionic conductors for oxygen permeation membrane. High electronic conductivity was observed for the Pr2 NiO4 system and the temperature dependence was of metal-like behavior, i.e., it decreased with elevating temperature. The oxygen permeability of Pr2 NiO4 -based oxides was much higher than that of La 2NiO 4-based oxides with the same K2 NiF4 -type structure. The effects of the Ni-site dopant were also studied and it was found that the oxygen permeation rate was improved by doping Cu and Mg. In particular, doping of Cu is most effective for enhancing the oxygen permeation rate from air to He, and the optimum concentration of Cu was found at 20%. The maximum permeability of 60 μmol min-1 cm-2 at 1273 K was attained using a 0.5 mm thick Pr2 Ni0.8 Cu0.2 O4 membrane. Addition of the excess Cu to Pr2 Ni0.8 Cu0.2 O4 significantly enhanced the oxygen permeation rate, probably due to the remarkable grain growth assisted by the formation of some Cu-containing liquid phase, and the oxygen permeation rate reached to 100 μmol min-1 cm-2 with the same conditions.

Original languageEnglish
Pages (from-to)B57-B62
JournalJournal of the Electrochemical Society
Volume154
Issue number1
DOIs
Publication statusPublished - Jan 1 2007

Fingerprint

Oxides
permeability
Permeation
Oxygen
conductivity
oxides
oxygen
Doping (additives)
membranes
Membranes
Grain growth
electronics
liquid phases
conductors
Metals
Temperature
temperature dependence
air
Liquids
Air

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

Cite this

Mixed conductivity and oxygen permeability of doped Pr 2 NiO 4 -based oxides. / Miyoshi, Shogo; Furuno, Tetsuro; Sangoanruang, Oravan; Matsumoto, Hiroshige; Ishihara, Tatsumi.

In: Journal of the Electrochemical Society, Vol. 154, No. 1, 01.01.2007, p. B57-B62.

Research output: Contribution to journalArticle

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AB - Pr2 NiO4 -based oxides were studied as a series of new mixed electronic and oxide-ionic conductors for oxygen permeation membrane. High electronic conductivity was observed for the Pr2 NiO4 system and the temperature dependence was of metal-like behavior, i.e., it decreased with elevating temperature. The oxygen permeability of Pr2 NiO4 -based oxides was much higher than that of La 2NiO 4-based oxides with the same K2 NiF4 -type structure. The effects of the Ni-site dopant were also studied and it was found that the oxygen permeation rate was improved by doping Cu and Mg. In particular, doping of Cu is most effective for enhancing the oxygen permeation rate from air to He, and the optimum concentration of Cu was found at 20%. The maximum permeability of 60 μmol min-1 cm-2 at 1273 K was attained using a 0.5 mm thick Pr2 Ni0.8 Cu0.2 O4 membrane. Addition of the excess Cu to Pr2 Ni0.8 Cu0.2 O4 significantly enhanced the oxygen permeation rate, probably due to the remarkable grain growth assisted by the formation of some Cu-containing liquid phase, and the oxygen permeation rate reached to 100 μmol min-1 cm-2 with the same conditions.

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