Mixed electronic-oxide ionic conductivity and oxygen permeating property of Fe-, Co- or Ni-doped LaGaO3 perovskite oxide

Tatsumi Ishihara, Takashi Yamada, Hiroshi Arikawa, Hiroyasu Nishiguchi, Yusaku Takita

Research output: Contribution to journalArticle

136 Citations (Scopus)

Abstract

Mixed electronic-oxide ionic conductivity in LaGaO3-based oxide doped with Fe, Co or Ni was investigated in this study. The electric conductivity was greatly increased by doping Fe, Co, or Ni for the Ga site of La0.8Sr0.2GaO3. Compared to the conventional mixed electronic-ionic conductors such as LaCoO3, these LaGaO3-based oxides exhibited a lower electronic conductivity but a higher oxide ion conductivity. In particular, Fe-doped LaGaO3 exhibited a high oxygen permeation rate and a stability against reduction. Consequently, higher CH4 conversion in the partial oxidation of CH4 was attained by using La0.8Sr0.2Ga0.6Fe0.4O3 in the place of the conventional candidate material of La0.6Sr0.4Fe0.8Co0.2O3 for the oxygen permeation membrane. As a result, this study revealed that LaGaO3-based oxide doped with Fe, Co or Ni for Ga site is a new family of mixed electronic-oxide ionic conductors.

Original languageEnglish
Pages (from-to)631-636
Number of pages6
JournalSolid State Ionics
Volume135
Issue number1-4
DOIs
Publication statusPublished - Nov 1 2000
Externally publishedYes

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permeating
Ionic conductivity
Perovskite
Oxides
ion currents
Oxygen
oxides
oxygen
electronics
Permeation
conductivity
conductors
perovskite
Doping (additives)
Ions
membranes
Membranes
Oxidation
oxidation

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Mixed electronic-oxide ionic conductivity and oxygen permeating property of Fe-, Co- or Ni-doped LaGaO3 perovskite oxide. / Ishihara, Tatsumi; Yamada, Takashi; Arikawa, Hiroshi; Nishiguchi, Hiroyasu; Takita, Yusaku.

In: Solid State Ionics, Vol. 135, No. 1-4, 01.11.2000, p. 631-636.

Research output: Contribution to journalArticle

Ishihara, Tatsumi ; Yamada, Takashi ; Arikawa, Hiroshi ; Nishiguchi, Hiroyasu ; Takita, Yusaku. / Mixed electronic-oxide ionic conductivity and oxygen permeating property of Fe-, Co- or Ni-doped LaGaO3 perovskite oxide. In: Solid State Ionics. 2000 ; Vol. 135, No. 1-4. pp. 631-636.
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AU - Yamada, Takashi

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AU - Nishiguchi, Hiroyasu

AU - Takita, Yusaku

PY - 2000/11/1

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N2 - Mixed electronic-oxide ionic conductivity in LaGaO3-based oxide doped with Fe, Co or Ni was investigated in this study. The electric conductivity was greatly increased by doping Fe, Co, or Ni for the Ga site of La0.8Sr0.2GaO3. Compared to the conventional mixed electronic-ionic conductors such as LaCoO3, these LaGaO3-based oxides exhibited a lower electronic conductivity but a higher oxide ion conductivity. In particular, Fe-doped LaGaO3 exhibited a high oxygen permeation rate and a stability against reduction. Consequently, higher CH4 conversion in the partial oxidation of CH4 was attained by using La0.8Sr0.2Ga0.6Fe0.4O3 in the place of the conventional candidate material of La0.6Sr0.4Fe0.8Co0.2O3 for the oxygen permeation membrane. As a result, this study revealed that LaGaO3-based oxide doped with Fe, Co or Ni for Ga site is a new family of mixed electronic-oxide ionic conductors.

AB - Mixed electronic-oxide ionic conductivity in LaGaO3-based oxide doped with Fe, Co or Ni was investigated in this study. The electric conductivity was greatly increased by doping Fe, Co, or Ni for the Ga site of La0.8Sr0.2GaO3. Compared to the conventional mixed electronic-ionic conductors such as LaCoO3, these LaGaO3-based oxides exhibited a lower electronic conductivity but a higher oxide ion conductivity. In particular, Fe-doped LaGaO3 exhibited a high oxygen permeation rate and a stability against reduction. Consequently, higher CH4 conversion in the partial oxidation of CH4 was attained by using La0.8Sr0.2Ga0.6Fe0.4O3 in the place of the conventional candidate material of La0.6Sr0.4Fe0.8Co0.2O3 for the oxygen permeation membrane. As a result, this study revealed that LaGaO3-based oxide doped with Fe, Co or Ni for Ga site is a new family of mixed electronic-oxide ionic conductors.

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