[Mn4III3-O)2(μ-O 2CMe)7(2,2′-bipyridine)2]ClO4

Tsuyoshi Tamane, Taro Tsubomura, Ken Sakai

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The anhydrous form of a known tetramanganese cluster, which was previously isolated in its trihydrate form, has been prepared from a different starting material. The new complex, bis(μ3-oxo)-1:2:4κ3O;2:3:4κ 3O-heptakis(μ-acetato)-1:2κ 4O:O′;1:4κ:2O:O′;2:3κ 2O:O′;2:4κ2-O:O′;3:4κ 4O:O′-bis(2,2′-bipyridine)-1κ 2N,N′3κ2N,N′-tetramanganese perchlorate, [Mn4(O)2(C2H3O2) 7 (C10H8N2)2]ClO4, crystallizes in the monoclinic space group C2/c, in a higher symmetry compared to the previous form. A crystallographic twofold axis passes through the centre of the molecule. The fundamental structure of the complex clearly resembles that of the form already reported.

Original languageEnglish
Pages (from-to)777-779
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume52
Issue number4
DOIs
Publication statusPublished - Apr 15 1996
Externally publishedYes

Fingerprint

Molecules
perchlorate

All Science Journal Classification (ASJC) codes

  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

[Mn4III3-O)2(μ-O 2CMe)7(2,2′-bipyridine)2]ClO4. / Tamane, Tsuyoshi; Tsubomura, Taro; Sakai, Ken.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 52, No. 4, 15.04.1996, p. 777-779.

Research output: Contribution to journalArticle

@article{77b049ed81e74cd8873dcd6df4a5bd4a,
title = "[Mn4III(μ3-O)2(μ-O 2CMe)7(2,2′-bipyridine)2]ClO4",
abstract = "The anhydrous form of a known tetramanganese cluster, which was previously isolated in its trihydrate form, has been prepared from a different starting material. The new complex, bis(μ3-oxo)-1:2:4κ3O;2:3:4κ 3O-heptakis(μ-acetato)-1:2κ 4O:O′;1:4κ:2O:O′;2:3κ 2O:O′;2:4κ2-O:O′;3:4κ 4O:O′-bis(2,2′-bipyridine)-1κ 2N,N′3κ2N,N′-tetramanganese perchlorate, [Mn4(O)2(C2H3O2) 7 (C10H8N2)2]ClO4, crystallizes in the monoclinic space group C2/c, in a higher symmetry compared to the previous form. A crystallographic twofold axis passes through the centre of the molecule. The fundamental structure of the complex clearly resembles that of the form already reported.",
author = "Tsuyoshi Tamane and Taro Tsubomura and Ken Sakai",
year = "1996",
month = "4",
day = "15",
doi = "10.1107/S0108270195013333",
language = "English",
volume = "52",
pages = "777--779",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
publisher = "International Union of Crystallography",
number = "4",

}

TY - JOUR

T1 - [Mn4III(μ3-O)2(μ-O 2CMe)7(2,2′-bipyridine)2]ClO4

AU - Tamane, Tsuyoshi

AU - Tsubomura, Taro

AU - Sakai, Ken

PY - 1996/4/15

Y1 - 1996/4/15

N2 - The anhydrous form of a known tetramanganese cluster, which was previously isolated in its trihydrate form, has been prepared from a different starting material. The new complex, bis(μ3-oxo)-1:2:4κ3O;2:3:4κ 3O-heptakis(μ-acetato)-1:2κ 4O:O′;1:4κ:2O:O′;2:3κ 2O:O′;2:4κ2-O:O′;3:4κ 4O:O′-bis(2,2′-bipyridine)-1κ 2N,N′3κ2N,N′-tetramanganese perchlorate, [Mn4(O)2(C2H3O2) 7 (C10H8N2)2]ClO4, crystallizes in the monoclinic space group C2/c, in a higher symmetry compared to the previous form. A crystallographic twofold axis passes through the centre of the molecule. The fundamental structure of the complex clearly resembles that of the form already reported.

AB - The anhydrous form of a known tetramanganese cluster, which was previously isolated in its trihydrate form, has been prepared from a different starting material. The new complex, bis(μ3-oxo)-1:2:4κ3O;2:3:4κ 3O-heptakis(μ-acetato)-1:2κ 4O:O′;1:4κ:2O:O′;2:3κ 2O:O′;2:4κ2-O:O′;3:4κ 4O:O′-bis(2,2′-bipyridine)-1κ 2N,N′3κ2N,N′-tetramanganese perchlorate, [Mn4(O)2(C2H3O2) 7 (C10H8N2)2]ClO4, crystallizes in the monoclinic space group C2/c, in a higher symmetry compared to the previous form. A crystallographic twofold axis passes through the centre of the molecule. The fundamental structure of the complex clearly resembles that of the form already reported.

UR - http://www.scopus.com/inward/record.url?scp=0030124899&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0030124899&partnerID=8YFLogxK

U2 - 10.1107/S0108270195013333

DO - 10.1107/S0108270195013333

M3 - Article

AN - SCOPUS:0030124899

VL - 52

SP - 777

EP - 779

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 4

ER -