[MnIII(salen)]6[FeIII(bpmb)(CN) 2]6·7H2O: A cyanide-bridged nanosized molecular wheel

Zhong Hai Ni, Hui Zhong Kou, Li Fang Zhang, Chunhua Ge, Ai Li Cui, Ru Ji Wang, Yadong Li, Osamu Sato

Research output: Contribution to journalArticle

165 Citations (Scopus)

Abstract

Heterometallic wheel: A cyanide-bridged heterometallic dodecanuclear complex featuring a nanosized molecular wheel has been synthesized based on magnetically anisotropic [Mn(salen)]+ and [Fe-(bpmb) (CN) 2]- building blocks. Magnetic studies reveal that the complex exhibits overall ferromagnetic intramolecular coupling (see picture) and frequency-dependent ac magnetic susceptibility. H2bpmb = 1,2-bis(pyridine-2- carboxamido)-4-methyl benzene. (Graph Presented).

Original languageEnglish
Pages (from-to)7742-7745
Number of pages4
JournalAngewandte Chemie - International Edition
Volume44
Issue number47
DOIs
Publication statusPublished - Dec 2 2005

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Cyanides
Wheels
Toluene
Magnetic susceptibility
Pyridine
Benzene
disalicylaldehyde ethylenediamine
pyridine
Mn-salen

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

[MnIII(salen)]6[FeIII(bpmb)(CN) 2]6·7H2O : A cyanide-bridged nanosized molecular wheel. / Ni, Zhong Hai; Kou, Hui Zhong; Zhang, Li Fang; Ge, Chunhua; Cui, Ai Li; Wang, Ru Ji; Li, Yadong; Sato, Osamu.

In: Angewandte Chemie - International Edition, Vol. 44, No. 47, 02.12.2005, p. 7742-7745.

Research output: Contribution to journalArticle

Ni, Zhong Hai ; Kou, Hui Zhong ; Zhang, Li Fang ; Ge, Chunhua ; Cui, Ai Li ; Wang, Ru Ji ; Li, Yadong ; Sato, Osamu. / [MnIII(salen)]6[FeIII(bpmb)(CN) 2]6·7H2O : A cyanide-bridged nanosized molecular wheel. In: Angewandte Chemie - International Edition. 2005 ; Vol. 44, No. 47. pp. 7742-7745.
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