[MnIII(salen)]6[FeIII(bpmb)(CN) 2]6·7H2O: A cyanide-bridged nanosized molecular wheel

Zhong Hai Ni; Hui Zhong Kou; Li Fang Zhang; Chunhua Ge; Ai Li Cui; Ru Ji Wang; Yadong Li; Osamu Sato

doi:10.1002/anie.200502699

[Mn^III(salen)]₆[Fe^III(bpmb)(CN) ₂]₆·7H₂O: A cyanide-bridged nanosized molecular wheel

Zhong Hai Ni, Hui Zhong Kou, Li Fang Zhang, Chunhua Ge, Ai Li Cui, Ru Ji Wang, Yadong Li, Osamu Sato

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

168 Citations (Scopus)

Abstract

Heterometallic wheel: A cyanide-bridged heterometallic dodecanuclear complex featuring a nanosized molecular wheel has been synthesized based on magnetically anisotropic [Mn(salen)]⁺ and [Fe-(bpmb) (CN) ₂]^- building blocks. Magnetic studies reveal that the complex exhibits overall ferromagnetic intramolecular coupling (see picture) and frequency-dependent ac magnetic susceptibility. H2bpmb = 1,2-bis(pyridine-2- carboxamido)-4-methyl benzene. (Graph Presented).

Original language	English
Pages (from-to)	7742-7745
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	47
DOIs	https://doi.org/10.1002/anie.200502699
Publication status	Published - Dec 2 2005

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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title = "[MnIII(salen)]6[FeIII(bpmb)(CN) 2]6·7H2O: A cyanide-bridged nanosized molecular wheel",

abstract = "Heterometallic wheel: A cyanide-bridged heterometallic dodecanuclear complex featuring a nanosized molecular wheel has been synthesized based on magnetically anisotropic [Mn(salen)]+ and [Fe-(bpmb) (CN) 2]- building blocks. Magnetic studies reveal that the complex exhibits overall ferromagnetic intramolecular coupling (see picture) and frequency-dependent ac magnetic susceptibility. H2bpmb = 1,2-bis(pyridine-2- carboxamido)-4-methyl benzene. (Graph Presented).",

author = "Ni, {Zhong Hai} and Kou, {Hui Zhong} and Zhang, {Li Fang} and Chunhua Ge and Cui, {Ai Li} and Wang, {Ru Ji} and Yadong Li and Osamu Sato",

year = "2005",

month = dec,

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doi = "10.1002/anie.200502699",

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journal = "Angewandte Chemie - International Edition",

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TY - JOUR

T1 - [MnIII(salen)]6[FeIII(bpmb)(CN) 2]6·7H2O

T2 - A cyanide-bridged nanosized molecular wheel

AU - Ni, Zhong Hai

AU - Kou, Hui Zhong

AU - Zhang, Li Fang

AU - Ge, Chunhua

AU - Cui, Ai Li

AU - Wang, Ru Ji

AU - Li, Yadong

AU - Sato, Osamu

PY - 2005/12/2

Y1 - 2005/12/2

N2 - Heterometallic wheel: A cyanide-bridged heterometallic dodecanuclear complex featuring a nanosized molecular wheel has been synthesized based on magnetically anisotropic [Mn(salen)]+ and [Fe-(bpmb) (CN) 2]- building blocks. Magnetic studies reveal that the complex exhibits overall ferromagnetic intramolecular coupling (see picture) and frequency-dependent ac magnetic susceptibility. H2bpmb = 1,2-bis(pyridine-2- carboxamido)-4-methyl benzene. (Graph Presented).

AB - Heterometallic wheel: A cyanide-bridged heterometallic dodecanuclear complex featuring a nanosized molecular wheel has been synthesized based on magnetically anisotropic [Mn(salen)]+ and [Fe-(bpmb) (CN) 2]- building blocks. Magnetic studies reveal that the complex exhibits overall ferromagnetic intramolecular coupling (see picture) and frequency-dependent ac magnetic susceptibility. H2bpmb = 1,2-bis(pyridine-2- carboxamido)-4-methyl benzene. (Graph Presented).

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[Mn^III(salen)]₆[Fe^III(bpmb)(CN) ₂]₆·7H₂O: A cyanide-bridged nanosized molecular wheel

Abstract

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