[MnIII(salen)]6[FeIII(bpmb)(CN) 2]6·7H2O: A cyanide-bridged nanosized molecular wheel

Zhong Hai Ni, Hui Zhong Kou, Li Fang Zhang, Chunhua Ge, Ai Li Cui, Ru Ji Wang, Yadong Li, Osamu Sato

Research output: Contribution to journalArticlepeer-review

168 Citations (Scopus)

Abstract

Heterometallic wheel: A cyanide-bridged heterometallic dodecanuclear complex featuring a nanosized molecular wheel has been synthesized based on magnetically anisotropic [Mn(salen)]+ and [Fe-(bpmb) (CN) 2]- building blocks. Magnetic studies reveal that the complex exhibits overall ferromagnetic intramolecular coupling (see picture) and frequency-dependent ac magnetic susceptibility. H2bpmb = 1,2-bis(pyridine-2- carboxamido)-4-methyl benzene. (Graph Presented).

Original languageEnglish
Pages (from-to)7742-7745
Number of pages4
JournalAngewandte Chemie - International Edition
Volume44
Issue number47
DOIs
Publication statusPublished - Dec 2 2005

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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