Modification of reactivity and strength of formed coke from victorian lignite by leaching of metallic species

Karnowo, Shinji Kudo, Aska Mori, Zayda Faizah Zahara, Koyo Norinaga, Jun Ichiro Hayashi

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Binderless briquetting of lignite at 100-200?C and subsequent carbonization produces formed coke with tensile strength (ST) of 5-40 MPa, while the briquetting often requires mechanical pressure over 100 MPa. High reactivity is another feature of the lignite-derived coke, and this arises from highly dispersed metallic species such as alkali/alkaline-earth metallic species and ferrous/ferric ones that catalyze CO2 gasification. This work investigated effects of leaching of those metallic species in aqueous solution of hydrochloric acid, acetic acid or oxalic acid on the reactivity and ST of resulting coke from a lignite. The leaching at pH ≤ 1 removed catalytic metallic species near completely, reducing the coke reactivity by a factor of 8-15. The reduced reactivity was similar to the reactivity of coke from a typical coking coal. The leaching at pH ≤?2.2 increased ST from 6 to 13 MPa for briquetting at 200°C and 32 MPa. The performance of leaching with oxalic acid, of that solution had pH of 0.75 at 1 mol/L, was much better than that with acetic acid. This work also examined another type of leaching, oxidation of the lignite in aqueous solution of hydrogen peroxide, which produced organic mono-/di-acids in-situ from the oxidation of aromatic carbons of the lignite. The degree of reduction of the coke reactivity was between that for leaching at pH of 1 and 2. The degradation of macromolecules enhanced plasticizability of the lignite under briquetting and increased ST of the resulting coke to 22 MPa.

Original languageEnglish
Pages (from-to)765-774
Number of pages10
Journalisij international
Volume55
Issue number4
DOIs
Publication statusPublished - Jan 1 2015

Fingerprint

Coal
Lignite
Coke
Leaching
Briquetting
Oxalic Acid
Oxalic acid
Acetic acid
Acetic Acid
Oxidation
Carbon
Hydrochloric Acid
Coking
Carbonization
Alkalies
Hydrochloric acid
Macromolecules
Gasification
Hydrogen peroxide
Hydrogen Peroxide

All Science Journal Classification (ASJC) codes

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Modification of reactivity and strength of formed coke from victorian lignite by leaching of metallic species. / Karnowo, ; Kudo, Shinji; Mori, Aska; Zahara, Zayda Faizah; Norinaga, Koyo; Hayashi, Jun Ichiro.

In: isij international, Vol. 55, No. 4, 01.01.2015, p. 765-774.

Research output: Contribution to journalArticle

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