Molecular dispersion of chains in the mixed-valence complexes [M(en)2][MCl2(en)2] (M: Pt, Pd, Ni) and anionic amphiphiles in organic media

Nobuo Kimizuka, Sang Ho Lee, Toyoki Kunitake

Research output: Contribution to journalArticlepeer-review

55 Citations (Scopus)

Abstract

A way to prepare molecular electronic wires in organic media is the solubilization of one-dimensional mixed-valence complexes with varied metal species through the formation of amphiphilic supramolecular assemblies (see picture). Dissociation and reassembly of the complex was detected as thermochromism in the intervalence (M(II) → M(IV)) absorption bands.

Original languageEnglish
Pages (from-to)389-391
Number of pages3
JournalAngewandte Chemie - International Edition
Volume39
Issue number2
DOIs
Publication statusPublished - Jan 17 2000

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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