Molecular dynamics study of the adhesion between end-grafted polymer films

Hiroshi Morita, Masamichi Yamada, Tetsuo Yamaguchi, Masao Doi

Research output: Contribution to conferencePaperpeer-review

Abstract

The adhesion between end-grafted polymer films is studied by coarse grained molecular dynamics simulations. We propose not only the one-end grafted (straight) polymer film but also the both-end grafted (loop) polymer film as a soft adhesive material, and we try to analyze the adhesive properties between them. From our simulations of the straight-straight adhesion system, the separation between the films occurs with forming the fibrils or the cavities. Fibril formation can only be seen at the lower temperature than the glass transition temperature of polymer film. On the other hand, cavity appears at the higher temperature. An adhesion force of the straight-loop system is much stronger than that of the straight-straight system. From our analysis, the difference of the adhesion forces between straight-straight and straight-loop systems can be explained by the mobility of the polymer chains in the films.

Original languageEnglish
Pages7-9
Number of pages3
Publication statusPublished - Oct 18 2006
Externally publishedYes
Event55th SPSJ Annual Meeting - Nagoya, Japan
Duration: May 24 2006May 26 2006

Other

Other55th SPSJ Annual Meeting
Country/TerritoryJapan
CityNagoya
Period5/24/065/26/06

All Science Journal Classification (ASJC) codes

  • Engineering(all)

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