Molecular motion in organometallic crystals: photoinduced 2π/5 rotation ofn-hexyltetramethylcyclopentadienyl ligand

Hidetaka Nakai, Yuu Kajiwara, Seiya Miyata

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Crystalline-state photoreaction of a newly prepared organorhodium dithionite complex withn-hexyltetramethyl-cyclopentadienyl (CpHex: η5-C5Me4n-Hexyl) ligands was studied by single crystal X-ray diffraction experiments; 2π/5 rotation of the CpHexligand is induced by the photoisomerization of the dithionite group (μ-O2SSO2).

Original languageEnglish
Pages (from-to)3790-3793
Number of pages4
JournalCrystEngComm
Volume23
Issue number21
DOIs
Publication statusPublished - Jun 7 2021
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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