Molecular orbital engineering of single-molecular light emission

Daijiro Nozaki; Kazunari Yoshizawa

doi:10.1016/j.cplett.2004.06.131

Molecular orbital engineering of single-molecular light emission

Daijiro Nozaki, Kazunari Yoshizawa

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A concept of single-molecular light emission is theoretically proposed by using a π-conjugated molecule linked by meta-phenylene couplers, gold as the anode, and calcium as the cathode. The molecule, which comprises perylene at the center as the light-emitting moiety and two phenylacetylenes as the hole- and electron-transporting moieties, is designed to have localized π-MOs with an appropriate energy gradient to efficiently transport carriers at the single-molecular level.

Original language	English
Pages (from-to)	194-197
Number of pages	4
Journal	Chemical Physics Letters
Volume	394
Issue number	1-3
DOIs	https://doi.org/10.1016/j.cplett.2004.06.131
Publication status	Published - Aug 11 2004

All Science Journal Classification (ASJC) codes

Physics and Astronomy(all)
Physical and Theoretical Chemistry

Access to Document

10.1016/j.cplett.2004.06.131

Fingerprint Dive into the research topics of 'Molecular orbital engineering of single-molecular light emission'. Together they form a unique fingerprint.

Cite this

@article{f9c408ca958d4d179d0cae08a26b8045,

title = "Molecular orbital engineering of single-molecular light emission",

abstract = "A concept of single-molecular light emission is theoretically proposed by using a π-conjugated molecule linked by meta-phenylene couplers, gold as the anode, and calcium as the cathode. The molecule, which comprises perylene at the center as the light-emitting moiety and two phenylacetylenes as the hole- and electron-transporting moieties, is designed to have localized π-MOs with an appropriate energy gradient to efficiently transport carriers at the single-molecular level.",

author = "Daijiro Nozaki and Kazunari Yoshizawa",

year = "2004",

month = aug,

day = "11",

doi = "10.1016/j.cplett.2004.06.131",

language = "English",

volume = "394",

pages = "194--197",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier",

number = "1-3",

}

TY - JOUR

T1 - Molecular orbital engineering of single-molecular light emission

AU - Nozaki, Daijiro

AU - Yoshizawa, Kazunari

PY - 2004/8/11

Y1 - 2004/8/11

N2 - A concept of single-molecular light emission is theoretically proposed by using a π-conjugated molecule linked by meta-phenylene couplers, gold as the anode, and calcium as the cathode. The molecule, which comprises perylene at the center as the light-emitting moiety and two phenylacetylenes as the hole- and electron-transporting moieties, is designed to have localized π-MOs with an appropriate energy gradient to efficiently transport carriers at the single-molecular level.

AB - A concept of single-molecular light emission is theoretically proposed by using a π-conjugated molecule linked by meta-phenylene couplers, gold as the anode, and calcium as the cathode. The molecule, which comprises perylene at the center as the light-emitting moiety and two phenylacetylenes as the hole- and electron-transporting moieties, is designed to have localized π-MOs with an appropriate energy gradient to efficiently transport carriers at the single-molecular level.

UR - http://www.scopus.com/inward/record.url?scp=3843124451&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=3843124451&partnerID=8YFLogxK

U2 - 10.1016/j.cplett.2004.06.131

DO - 10.1016/j.cplett.2004.06.131

M3 - Article

AN - SCOPUS:3843124451

VL - 394

SP - 194

EP - 197

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 1-3

ER -