Abstract
A concept of single-molecular light emission is theoretically proposed by using a π-conjugated molecule linked by meta-phenylene couplers, gold as the anode, and calcium as the cathode. The molecule, which comprises perylene at the center as the light-emitting moiety and two phenylacetylenes as the hole- and electron-transporting moieties, is designed to have localized π-MOs with an appropriate energy gradient to efficiently transport carriers at the single-molecular level.
| Original language | English |
|---|---|
| Pages (from-to) | 194-197 |
| Number of pages | 4 |
| Journal | Chemical Physics Letters |
| Volume | 394 |
| Issue number | 1-3 |
| DOIs | |
| Publication status | Published - Aug 11 2004 |
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All Science Journal Classification (ASJC) codes
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
Cite this
Molecular orbital engineering of single-molecular light emission. / Nozaki, Daijiro; Yoshizawa, Kazunari.
In: Chemical Physics Letters, Vol. 394, No. 1-3, 11.08.2004, p. 194-197.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Molecular orbital engineering of single-molecular light emission
AU - Nozaki, Daijiro
AU - Yoshizawa, Kazunari
PY - 2004/8/11
Y1 - 2004/8/11
N2 - A concept of single-molecular light emission is theoretically proposed by using a π-conjugated molecule linked by meta-phenylene couplers, gold as the anode, and calcium as the cathode. The molecule, which comprises perylene at the center as the light-emitting moiety and two phenylacetylenes as the hole- and electron-transporting moieties, is designed to have localized π-MOs with an appropriate energy gradient to efficiently transport carriers at the single-molecular level.
AB - A concept of single-molecular light emission is theoretically proposed by using a π-conjugated molecule linked by meta-phenylene couplers, gold as the anode, and calcium as the cathode. The molecule, which comprises perylene at the center as the light-emitting moiety and two phenylacetylenes as the hole- and electron-transporting moieties, is designed to have localized π-MOs with an appropriate energy gradient to efficiently transport carriers at the single-molecular level.
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UR - http://www.scopus.com/inward/citedby.url?scp=3843124451&partnerID=8YFLogxK
U2 - 10.1016/j.cplett.2004.06.131
DO - 10.1016/j.cplett.2004.06.131
M3 - Article
AN - SCOPUS:3843124451
VL - 394
SP - 194
EP - 197
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 1-3
ER -