TY - JOUR
T1 - Molecular orbital engineering of single-molecular light emission
AU - Nozaki, Daijiro
AU - Yoshizawa, Kazunari
N1 - Funding Information:
K.Y. acknowledges the Ministry of Culture, Sports, Science and Technology of Japan (MEXT), Japan Society for the Promotion of Science, ‘Nanotechnology Support Project’ of MEXT, Japan Science and Technology Cooperation, the Murata Science Foundation, and Kyushu University P&P ‘GreenChemistry’ for their support of this work.
PY - 2004/8/11
Y1 - 2004/8/11
N2 - A concept of single-molecular light emission is theoretically proposed by using a π-conjugated molecule linked by meta-phenylene couplers, gold as the anode, and calcium as the cathode. The molecule, which comprises perylene at the center as the light-emitting moiety and two phenylacetylenes as the hole- and electron-transporting moieties, is designed to have localized π-MOs with an appropriate energy gradient to efficiently transport carriers at the single-molecular level.
AB - A concept of single-molecular light emission is theoretically proposed by using a π-conjugated molecule linked by meta-phenylene couplers, gold as the anode, and calcium as the cathode. The molecule, which comprises perylene at the center as the light-emitting moiety and two phenylacetylenes as the hole- and electron-transporting moieties, is designed to have localized π-MOs with an appropriate energy gradient to efficiently transport carriers at the single-molecular level.
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U2 - 10.1016/j.cplett.2004.06.131
DO - 10.1016/j.cplett.2004.06.131
M3 - Article
AN - SCOPUS:3843124451
VL - 394
SP - 194
EP - 197
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 1-3
ER -