Molecular programming based on complexation between Pybox ligands and sec-dialkylammonium cations

Kazuki Sada, Takayuki Suzuki, Takahiro Sugimoto, Takahiro Tani, Yuzo Fujiki, Daisuke Kikuno, Seiji Shinkai

Research output: Contribution to conferencePaper

Abstract

Control of number and order in the supramolecular assemblies have been of much interest due to their application for informational technology and mimetic approaches for molecular information of biological polymers such as DNA and proteins. We previously reported that 2,6-bis(2-oxazolyl)pyridine (Pybox) forms the 1:1 complexes with various secondary dialkylammonium cations as a tool for supramolecular assemblies. In this report, we demonstrate formation of ordered supramolecular assembly from two different pybox (P) and bzpybox (B) ligands by complexation with dimeric imminium cation (IA) as a template. The two ammonium sites of IA were differentiated by steric repulsion between the phthalimide moieties of IA and macrocyclic structure of P. 1H-NMR titration indicated that IA form a 1:1:1 complex with P and B.

Original languageEnglish
Pages4324-4325
Number of pages2
Publication statusPublished - Dec 1 2005
Event54th SPSJ Symposium on Macromolecules - Yamagata, Japan
Duration: Sep 20 2005Sep 22 2005

Other

Other54th SPSJ Symposium on Macromolecules
CountryJapan
CityYamagata
Period9/20/059/22/05

Fingerprint

Complexation
Positive ions
Ligands
Titration
Pyridine
DNA
Nuclear magnetic resonance
Proteins
Polymers

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Sada, K., Suzuki, T., Sugimoto, T., Tani, T., Fujiki, Y., Kikuno, D., & Shinkai, S. (2005). Molecular programming based on complexation between Pybox ligands and sec-dialkylammonium cations. 4324-4325. Paper presented at 54th SPSJ Symposium on Macromolecules, Yamagata, Japan.

Molecular programming based on complexation between Pybox ligands and sec-dialkylammonium cations. / Sada, Kazuki; Suzuki, Takayuki; Sugimoto, Takahiro; Tani, Takahiro; Fujiki, Yuzo; Kikuno, Daisuke; Shinkai, Seiji.

2005. 4324-4325 Paper presented at 54th SPSJ Symposium on Macromolecules, Yamagata, Japan.

Research output: Contribution to conferencePaper

Sada, K, Suzuki, T, Sugimoto, T, Tani, T, Fujiki, Y, Kikuno, D & Shinkai, S 2005, 'Molecular programming based on complexation between Pybox ligands and sec-dialkylammonium cations' Paper presented at 54th SPSJ Symposium on Macromolecules, Yamagata, Japan, 9/20/05 - 9/22/05, pp. 4324-4325.
Sada K, Suzuki T, Sugimoto T, Tani T, Fujiki Y, Kikuno D et al. Molecular programming based on complexation between Pybox ligands and sec-dialkylammonium cations. 2005. Paper presented at 54th SPSJ Symposium on Macromolecules, Yamagata, Japan.
Sada, Kazuki ; Suzuki, Takayuki ; Sugimoto, Takahiro ; Tani, Takahiro ; Fujiki, Yuzo ; Kikuno, Daisuke ; Shinkai, Seiji. / Molecular programming based on complexation between Pybox ligands and sec-dialkylammonium cations. Paper presented at 54th SPSJ Symposium on Macromolecules, Yamagata, Japan.2 p.
@conference{384857b99abb40b9a8a60bdde5d5ef5c,
title = "Molecular programming based on complexation between Pybox ligands and sec-dialkylammonium cations",
abstract = "Control of number and order in the supramolecular assemblies have been of much interest due to their application for informational technology and mimetic approaches for molecular information of biological polymers such as DNA and proteins. We previously reported that 2,6-bis(2-oxazolyl)pyridine (Pybox) forms the 1:1 complexes with various secondary dialkylammonium cations as a tool for supramolecular assemblies. In this report, we demonstrate formation of ordered supramolecular assembly from two different pybox (P) and bzpybox (B) ligands by complexation with dimeric imminium cation (IA) as a template. The two ammonium sites of IA were differentiated by steric repulsion between the phthalimide moieties of IA and macrocyclic structure of P. 1H-NMR titration indicated that IA form a 1:1:1 complex with P and B.",
author = "Kazuki Sada and Takayuki Suzuki and Takahiro Sugimoto and Takahiro Tani and Yuzo Fujiki and Daisuke Kikuno and Seiji Shinkai",
year = "2005",
month = "12",
day = "1",
language = "English",
pages = "4324--4325",
note = "54th SPSJ Symposium on Macromolecules ; Conference date: 20-09-2005 Through 22-09-2005",

}

TY - CONF

T1 - Molecular programming based on complexation between Pybox ligands and sec-dialkylammonium cations

AU - Sada, Kazuki

AU - Suzuki, Takayuki

AU - Sugimoto, Takahiro

AU - Tani, Takahiro

AU - Fujiki, Yuzo

AU - Kikuno, Daisuke

AU - Shinkai, Seiji

PY - 2005/12/1

Y1 - 2005/12/1

N2 - Control of number and order in the supramolecular assemblies have been of much interest due to their application for informational technology and mimetic approaches for molecular information of biological polymers such as DNA and proteins. We previously reported that 2,6-bis(2-oxazolyl)pyridine (Pybox) forms the 1:1 complexes with various secondary dialkylammonium cations as a tool for supramolecular assemblies. In this report, we demonstrate formation of ordered supramolecular assembly from two different pybox (P) and bzpybox (B) ligands by complexation with dimeric imminium cation (IA) as a template. The two ammonium sites of IA were differentiated by steric repulsion between the phthalimide moieties of IA and macrocyclic structure of P. 1H-NMR titration indicated that IA form a 1:1:1 complex with P and B.

AB - Control of number and order in the supramolecular assemblies have been of much interest due to their application for informational technology and mimetic approaches for molecular information of biological polymers such as DNA and proteins. We previously reported that 2,6-bis(2-oxazolyl)pyridine (Pybox) forms the 1:1 complexes with various secondary dialkylammonium cations as a tool for supramolecular assemblies. In this report, we demonstrate formation of ordered supramolecular assembly from two different pybox (P) and bzpybox (B) ligands by complexation with dimeric imminium cation (IA) as a template. The two ammonium sites of IA were differentiated by steric repulsion between the phthalimide moieties of IA and macrocyclic structure of P. 1H-NMR titration indicated that IA form a 1:1:1 complex with P and B.

UR - http://www.scopus.com/inward/record.url?scp=33645557772&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33645557772&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:33645557772

SP - 4324

EP - 4325

ER -