Molecular stacking induced by intermolecular C-H⋯N hydrogen bonds leading to high carrier mobility in vacuum-deposited organic films

Daisuke Yokoyama, Hisahiro Sasabe, Yukio Furukawa, Chihaya Adachi, Junji Kido

Research output: Contribution to journalArticle

99 Citations (Scopus)

Abstract

Simple bottom-up fabrication processes for molecular self-assembly have been developed for the construction of higher-order structures using organic materials, and have contributed to maximization of the potential of organic materials in chemical and bioengineering. However, their application to organic thin-film devices such as organic light-emitting diodes have not been widely considered because simple fabrication of a solid film containing an internal self-assembly structure has been regarded as difficult. Here it is shown that the intermolecular C-H···N hydrogen bonds can be simply formed even in vacuum-deposited organic films having flat interfaces. By designing the molecules containing pyridine rings properly for the intermolecular interaction, one can control the molecular stacking induced by the intermolecular hydrogen bonds. It is also demonstrated that the molecular stacking contributes to the high carrier mobility of the film. These findings provide new guidelines to improve the performance of organic optoelectronic devices and open up the possibilities for further development of organic devices with higher-order structures.

Original languageEnglish
Pages (from-to)1375-1382
Number of pages8
JournalAdvanced Functional Materials
Volume21
Issue number8
DOIs
Publication statusPublished - Apr 22 2011

Fingerprint

Carrier mobility
carrier mobility
Hydrogen bonds
Vacuum
hydrogen bonds
organic materials
Self assembly
vacuum
self assembly
bioengineering
Thin film devices
Fabrication
fabrication
Organic light emitting diodes (OLED)
optoelectronic devices
Optoelectronic devices
Pyridine
pyridines
light emitting diodes
Molecules

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Condensed Matter Physics
  • Electrochemistry

Cite this

Molecular stacking induced by intermolecular C-H⋯N hydrogen bonds leading to high carrier mobility in vacuum-deposited organic films. / Yokoyama, Daisuke; Sasabe, Hisahiro; Furukawa, Yukio; Adachi, Chihaya; Kido, Junji.

In: Advanced Functional Materials, Vol. 21, No. 8, 22.04.2011, p. 1375-1382.

Research output: Contribution to journalArticle

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