Molybdenum-Catalyzed Ammonia Formation Using Simple Monodentate and Bidentate Phosphines as Auxiliary Ligands

Yuya Ashida, Kazuya Arashiba, Hiromasa Tanaka, Akihito Egi, Kazunari Nakajima, Kazunari Yoshizawa, Yoshiaki Nishibayashi

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

We have found molybdenum-catalyzed ammonia formation using simple and commercially available monodentate and bidentate phosphines as auxiliary ligands with a simple and convenient procedure. Molybdenum complexes generated in situ from [MoI3(THF)3] and the corresponding phosphines such as PMePh2 and 1,5-bis(diphenylphosphino)pentane worked effectively toward ammonia formation.

Original languageEnglish
Pages (from-to)8927-8932
Number of pages6
JournalInorganic chemistry
Volume58
Issue number14
DOIs
Publication statusPublished - Jul 15 2019

Fingerprint

Phosphines
Molybdenum
Ammonia
phosphines
molybdenum
ammonia
Ligands
ligands
pentanes
pentane

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Molybdenum-Catalyzed Ammonia Formation Using Simple Monodentate and Bidentate Phosphines as Auxiliary Ligands. / Ashida, Yuya; Arashiba, Kazuya; Tanaka, Hiromasa; Egi, Akihito; Nakajima, Kazunari; Yoshizawa, Kazunari; Nishibayashi, Yoshiaki.

In: Inorganic chemistry, Vol. 58, No. 14, 15.07.2019, p. 8927-8932.

Research output: Contribution to journalArticle

Ashida, Yuya ; Arashiba, Kazuya ; Tanaka, Hiromasa ; Egi, Akihito ; Nakajima, Kazunari ; Yoshizawa, Kazunari ; Nishibayashi, Yoshiaki. / Molybdenum-Catalyzed Ammonia Formation Using Simple Monodentate and Bidentate Phosphines as Auxiliary Ligands. In: Inorganic chemistry. 2019 ; Vol. 58, No. 14. pp. 8927-8932.
@article{c84de0869ee04ef2b2d11265bb82c0aa,
title = "Molybdenum-Catalyzed Ammonia Formation Using Simple Monodentate and Bidentate Phosphines as Auxiliary Ligands",
abstract = "We have found molybdenum-catalyzed ammonia formation using simple and commercially available monodentate and bidentate phosphines as auxiliary ligands with a simple and convenient procedure. Molybdenum complexes generated in situ from [MoI3(THF)3] and the corresponding phosphines such as PMePh2 and 1,5-bis(diphenylphosphino)pentane worked effectively toward ammonia formation.",
author = "Yuya Ashida and Kazuya Arashiba and Hiromasa Tanaka and Akihito Egi and Kazunari Nakajima and Kazunari Yoshizawa and Yoshiaki Nishibayashi",
year = "2019",
month = "7",
day = "15",
doi = "10.1021/acs.inorgchem.9b01340",
language = "English",
volume = "58",
pages = "8927--8932",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "14",

}

TY - JOUR

T1 - Molybdenum-Catalyzed Ammonia Formation Using Simple Monodentate and Bidentate Phosphines as Auxiliary Ligands

AU - Ashida, Yuya

AU - Arashiba, Kazuya

AU - Tanaka, Hiromasa

AU - Egi, Akihito

AU - Nakajima, Kazunari

AU - Yoshizawa, Kazunari

AU - Nishibayashi, Yoshiaki

PY - 2019/7/15

Y1 - 2019/7/15

N2 - We have found molybdenum-catalyzed ammonia formation using simple and commercially available monodentate and bidentate phosphines as auxiliary ligands with a simple and convenient procedure. Molybdenum complexes generated in situ from [MoI3(THF)3] and the corresponding phosphines such as PMePh2 and 1,5-bis(diphenylphosphino)pentane worked effectively toward ammonia formation.

AB - We have found molybdenum-catalyzed ammonia formation using simple and commercially available monodentate and bidentate phosphines as auxiliary ligands with a simple and convenient procedure. Molybdenum complexes generated in situ from [MoI3(THF)3] and the corresponding phosphines such as PMePh2 and 1,5-bis(diphenylphosphino)pentane worked effectively toward ammonia formation.

UR - http://www.scopus.com/inward/record.url?scp=85068347186&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85068347186&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.9b01340

DO - 10.1021/acs.inorgchem.9b01340

M3 - Article

AN - SCOPUS:85068347186

VL - 58

SP - 8927

EP - 8932

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 14

ER -