Molybdenum-Catalyzed Ammonia Formation Using Simple Monodentate and Bidentate Phosphines as Auxiliary Ligands

Yuya Ashida, Kazuya Arashiba, Hiromasa Tanaka, Akihito Egi, Kazunari Nakajima, Kazunari Yoshizawa, Yoshiaki Nishibayashi

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

We have found molybdenum-catalyzed ammonia formation using simple and commercially available monodentate and bidentate phosphines as auxiliary ligands with a simple and convenient procedure. Molybdenum complexes generated in situ from [MoI3(THF)3] and the corresponding phosphines such as PMePh2 and 1,5-bis(diphenylphosphino)pentane worked effectively toward ammonia formation.

Original languageEnglish
Pages (from-to)8927-8932
Number of pages6
JournalInorganic chemistry
Volume58
Issue number14
DOIs
Publication statusPublished - Jul 15 2019

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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