Monometallic and heterobimetallic azanickellacycles as ethylene polymerization catalysts

Masao Tanabiki, Kazuhiro Tsuchiya, Yukihiro Motoyama, Hideo Nagashima

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

The azanickellacyclic complex (1) produced by trimerization of an isocyanide on the nickel atom is found to be a new ethylene polymerization catalyst; catalytic activity is increased by incorporation of the second metal to a diimino moiety of 1 leading to formation of heterobimetallic complexes.

Original languageEnglish
Pages (from-to)3409-3411
Number of pages3
JournalChemical Communications
Issue number27
DOIs
Publication statusPublished - Jul 21 2005

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Cyanides
Nickel
Catalyst activity
Ethylene
Metals
Polymerization
Atoms
Catalysts
ethylene

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Monometallic and heterobimetallic azanickellacycles as ethylene polymerization catalysts. / Tanabiki, Masao; Tsuchiya, Kazuhiro; Motoyama, Yukihiro; Nagashima, Hideo.

In: Chemical Communications, No. 27, 21.07.2005, p. 3409-3411.

Research output: Contribution to journalArticle

Tanabiki, Masao ; Tsuchiya, Kazuhiro ; Motoyama, Yukihiro ; Nagashima, Hideo. / Monometallic and heterobimetallic azanickellacycles as ethylene polymerization catalysts. In: Chemical Communications. 2005 ; No. 27. pp. 3409-3411.
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