Morphological evolution of vertically standing molybdenum disulfide nanosheets by chemical vapor deposition

Song Zhang, Jiajia Liu, Karla Hernandez Ruiz, Rong Tu, Meijun Yang, Qizhong Li, Ji Shi, Haiwen Li, Lianmeng Zhang, Takashi Goto

Research output: Contribution to journalArticle

Abstract

In this study, we demonstrated the chemical vapor deposition (CVD) of vertically standing molybdenum disulfide (MoS2) nanosheets, with an unconventional combination of molybdenum hexacarbonyl (Mo(CO)6) and 1,2-ethanedithiol (C2H6S2) as the novel kind of Mo and S precursors respectively. The effect of the distance between the precursor's outlet and substrates (denoted as d) on the growth characteristics of MoS2, including surface morphology and nanosheet structure, was investigated. Meanwhile, the relationship between the structure characteristics of MoS2 nanosheets and their catalytic performance for hydrogen evolution reaction (HER) was elucidated. The formation of vertically standing nanosheets was analyzed and verified by means of an extrusion growth model. The crystallinity, average length, and average depth between peak and valley (Rz) of MoS2 nanosheets differed depending on the spatial location of the substrate. Good crystalized MoS2 nanosheets grown at d = 5.5 cm with the largest average length of 440 nm, and the highest Rz of 162 nm contributed to a better HER performance, with a respective Tafel slope and exchange current density of 138.9 mV/decade, and 22.6 μA/cm2 for raw data (127.8 mV/decade and 19.3 μA/cm2 for iR-corrected data).

Original languageEnglish
Article number631
JournalMaterials
Volume11
Issue number4
DOIs
Publication statusPublished - Apr 20 2018

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Nanosheets
Molybdenum
Chemical vapor deposition
Hydrogen
Substrates
Surface morphology
Extrusion
molybdenum disulfide
Current density

All Science Journal Classification (ASJC) codes

  • Materials Science(all)

Cite this

Morphological evolution of vertically standing molybdenum disulfide nanosheets by chemical vapor deposition. / Zhang, Song; Liu, Jiajia; Ruiz, Karla Hernandez; Tu, Rong; Yang, Meijun; Li, Qizhong; Shi, Ji; Li, Haiwen; Zhang, Lianmeng; Goto, Takashi.

In: Materials, Vol. 11, No. 4, 631, 20.04.2018.

Research output: Contribution to journalArticle

Zhang, S, Liu, J, Ruiz, KH, Tu, R, Yang, M, Li, Q, Shi, J, Li, H, Zhang, L & Goto, T 2018, 'Morphological evolution of vertically standing molybdenum disulfide nanosheets by chemical vapor deposition', Materials, vol. 11, no. 4, 631. https://doi.org/10.3390/ma11040631
Zhang, Song ; Liu, Jiajia ; Ruiz, Karla Hernandez ; Tu, Rong ; Yang, Meijun ; Li, Qizhong ; Shi, Ji ; Li, Haiwen ; Zhang, Lianmeng ; Goto, Takashi. / Morphological evolution of vertically standing molybdenum disulfide nanosheets by chemical vapor deposition. In: Materials. 2018 ; Vol. 11, No. 4.
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