Mullite precursor part I. Characterization of mullite precursor formed by a reaction of monosilicic acid on aluminum hydroxide

Takushi Yokoyama; Keisuki Nishu; Shunsuke Torii; Yoshio Ikeda; Tokuko Watanabe

doi:10.1557/JMR.1997.0283

Mullite precursor part I. Characterization of mullite precursor formed by a reaction of monosilicic acid on aluminum hydroxide

Takushi Yokoyama, Keisuki Nishu, Shunsuke Torii, Yoshio Ikeda, Tokuko Watanabe

Inorganic and Analytical Chemistry

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

By adsorption of monosilicic acid on aluminum hydroxide, an amorphous aluminosilicate (AAS) of Si/Al ratio of 1/3 was formed. When the AAS was heated to 1000°C, mullite (3Al₂O₃ · 2SiO₂) crystallized directly without the formation of a spinel phase. It was clearly evidenced that correct adjustment of three factors, the Si/Al ratio, the proportion of 4- and 6-coordinated aluminums, and the single environment of a SiO^4-₄ unit (no Si-O-Si bond), is important for the direct mullitization from AAS.

Original language	English
Pages (from-to)	2111-2116
Number of pages	6
Journal	Journal of Materials Research
Volume	12
Issue number	8
DOIs	https://doi.org/10.1557/JMR.1997.0283
Publication status	Published - Aug 1997

All Science Journal Classification (ASJC) codes

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Access to Document

10.1557/JMR.1997.0283

Cite this

@article{150c7da693e34548b1927eefa2d80257,

title = "Mullite precursor part I. Characterization of mullite precursor formed by a reaction of monosilicic acid on aluminum hydroxide",

abstract = "By adsorption of monosilicic acid on aluminum hydroxide, an amorphous aluminosilicate (AAS) of Si/Al ratio of 1/3 was formed. When the AAS was heated to 1000°C, mullite (3Al2O3 · 2SiO2) crystallized directly without the formation of a spinel phase. It was clearly evidenced that correct adjustment of three factors, the Si/Al ratio, the proportion of 4- and 6-coordinated aluminums, and the single environment of a SiO4-4 unit (no Si-O-Si bond), is important for the direct mullitization from AAS.",

author = "Takushi Yokoyama and Keisuki Nishu and Shunsuke Torii and Yoshio Ikeda and Tokuko Watanabe",

year = "1997",

month = aug,

doi = "10.1557/JMR.1997.0283",

language = "English",

volume = "12",

pages = "2111--2116",

journal = "Journal of Materials Research",

issn = "0884-2914",

publisher = "Materials Research Society",

number = "8",

}

TY - JOUR

T1 - Mullite precursor part I. Characterization of mullite precursor formed by a reaction of monosilicic acid on aluminum hydroxide

AU - Yokoyama, Takushi

AU - Nishu, Keisuki

AU - Torii, Shunsuke

AU - Ikeda, Yoshio

AU - Watanabe, Tokuko

PY - 1997/8

Y1 - 1997/8

N2 - By adsorption of monosilicic acid on aluminum hydroxide, an amorphous aluminosilicate (AAS) of Si/Al ratio of 1/3 was formed. When the AAS was heated to 1000°C, mullite (3Al2O3 · 2SiO2) crystallized directly without the formation of a spinel phase. It was clearly evidenced that correct adjustment of three factors, the Si/Al ratio, the proportion of 4- and 6-coordinated aluminums, and the single environment of a SiO4-4 unit (no Si-O-Si bond), is important for the direct mullitization from AAS.

AB - By adsorption of monosilicic acid on aluminum hydroxide, an amorphous aluminosilicate (AAS) of Si/Al ratio of 1/3 was formed. When the AAS was heated to 1000°C, mullite (3Al2O3 · 2SiO2) crystallized directly without the formation of a spinel phase. It was clearly evidenced that correct adjustment of three factors, the Si/Al ratio, the proportion of 4- and 6-coordinated aluminums, and the single environment of a SiO4-4 unit (no Si-O-Si bond), is important for the direct mullitization from AAS.

UR - http://www.scopus.com/inward/record.url?scp=0031209987&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0031209987&partnerID=8YFLogxK

U2 - 10.1557/JMR.1997.0283

DO - 10.1557/JMR.1997.0283

M3 - Article

AN - SCOPUS:0031209987

SN - 0884-2914

VL - 12

SP - 2111

EP - 2116

JO - Journal of Materials Research

JF - Journal of Materials Research

IS - 8

ER -

Mullite precursor part I. Characterization of mullite precursor formed by a reaction of monosilicic acid on aluminum hydroxide

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this