Multifunctional nitrogen-doped carbon dots from maleic anhydride and tetraethylenepentamine via pyrolysis for sensing, adsorbance, and imaging applications

Nichaphat Thongsai, Yusuke Nagae, Tomoyasu Hirai, Atsushi Takahara, Tomoki Uchiyama, Kazutaka Kamitani, Peerasak Paoprasert

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Carbon dots are materials with fascinating optical and electronic properties that can replace organic dyes and fluorescent semiconductor nanocrystals. In this work, we developed a one-step pyrolysis for producing fluorescent, water-soluble, and highly nitrogen-doped carbon dots (NCDs) from the readily available chemical precursors: tetraethylenepentamine and maleic anhydride. NCDs exhibited blue fluorescent emission with a relatively high quantum yield of 21% and average diameter of approximately 8 nm. These NCDs were found to be selective sensors for Cu2+, with a limit of detection of 0.62 μM. A simple NCD-coated, paper-based sensor demonstrated that the NCDs were highly responsive to and selective of Cu2+. Furthermore, X-ray absorption fine structure measurements showed the unique coordinating properties of the NCDs. The copper complex changed from a distorted octahedral to a square planar structure upon the addition of NCDs. The NCDs were also found to be an excellent adsorbent for Cu2+, with a surface coverage of 1.5 ions nm−2, equivalent to 214 mg g−1 adsorption capacity. In addition, NCDs were used to image a human fingerprint and for the preparation of fluorescent plastics. These results demonstrated that the multifunctional NCDs with excellent optical properties and water solubility produced in this work can be used in a range of applications, including sensors, adsorbents, imaging, and forensic science.

Original languageEnglish
Pages (from-to)1026-1033
Number of pages8
JournalSensors and Actuators, B: Chemical
Volume253
DOIs
Publication statusPublished - Jan 1 2017

Fingerprint

Maleic Anhydrides
Maleic anhydride
anhydrides
pyrolysis
Pyrolysis
Nitrogen
Carbon
Imaging techniques
nitrogen
carbon
adsorbents
Adsorbents
sensors
Sensors
tetraethylenepentamine
Optical properties
law (jurisprudence)
optical properties
Water
planar structures

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Instrumentation
  • Condensed Matter Physics
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Electrical and Electronic Engineering
  • Materials Chemistry

Cite this

Multifunctional nitrogen-doped carbon dots from maleic anhydride and tetraethylenepentamine via pyrolysis for sensing, adsorbance, and imaging applications. / Thongsai, Nichaphat; Nagae, Yusuke; Hirai, Tomoyasu; Takahara, Atsushi; Uchiyama, Tomoki; Kamitani, Kazutaka; Paoprasert, Peerasak.

In: Sensors and Actuators, B: Chemical, Vol. 253, 01.01.2017, p. 1026-1033.

Research output: Contribution to journalArticle

Thongsai, Nichaphat ; Nagae, Yusuke ; Hirai, Tomoyasu ; Takahara, Atsushi ; Uchiyama, Tomoki ; Kamitani, Kazutaka ; Paoprasert, Peerasak. / Multifunctional nitrogen-doped carbon dots from maleic anhydride and tetraethylenepentamine via pyrolysis for sensing, adsorbance, and imaging applications. In: Sensors and Actuators, B: Chemical. 2017 ; Vol. 253. pp. 1026-1033.
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