Multiple conformational changes of β-tetraphenyl meso- hexakis(pentafluorophenyl) substituted [26] and [28]hexaphyrins(1.1.1.1.1.1)

Taro Koide, Katsuyuki Youfu, Shohei Saito, Atsuhiro Osuka

Research output: Contribution to journalArticle

46 Citations (Scopus)

Abstract

β-Tetraphenyl meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin 3 is conformationally flexible between rectangular and figure-of-eight shapes and its two-electron reduced [28]hexaphyrin 4 takes figure-of-eight conformations, which are changed, upon protonation, to twisted conformations with distinct Möbius aromaticity.

Original languageEnglish
Pages (from-to)6047-6049
Number of pages3
JournalChemical Communications
Issue number40
DOIs
Publication statusPublished - Dec 1 2009

Fingerprint

Conformations
Protonation
Electrons

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Multiple conformational changes of β-tetraphenyl meso- hexakis(pentafluorophenyl) substituted [26] and [28]hexaphyrins(1.1.1.1.1.1). / Koide, Taro; Youfu, Katsuyuki; Saito, Shohei; Osuka, Atsuhiro.

In: Chemical Communications, No. 40, 01.12.2009, p. 6047-6049.

Research output: Contribution to journalArticle

@article{7be8deb6fbc54767a355a373698616a0,
title = "Multiple conformational changes of β-tetraphenyl meso- hexakis(pentafluorophenyl) substituted [26] and [28]hexaphyrins(1.1.1.1.1.1)",
abstract = "β-Tetraphenyl meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin 3 is conformationally flexible between rectangular and figure-of-eight shapes and its two-electron reduced [28]hexaphyrin 4 takes figure-of-eight conformations, which are changed, upon protonation, to twisted conformations with distinct M{\"o}bius aromaticity.",
author = "Taro Koide and Katsuyuki Youfu and Shohei Saito and Atsuhiro Osuka",
year = "2009",
month = "12",
day = "1",
doi = "10.1039/b910167e",
language = "English",
pages = "6047--6049",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "40",

}

TY - JOUR

T1 - Multiple conformational changes of β-tetraphenyl meso- hexakis(pentafluorophenyl) substituted [26] and [28]hexaphyrins(1.1.1.1.1.1)

AU - Koide, Taro

AU - Youfu, Katsuyuki

AU - Saito, Shohei

AU - Osuka, Atsuhiro

PY - 2009/12/1

Y1 - 2009/12/1

N2 - β-Tetraphenyl meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin 3 is conformationally flexible between rectangular and figure-of-eight shapes and its two-electron reduced [28]hexaphyrin 4 takes figure-of-eight conformations, which are changed, upon protonation, to twisted conformations with distinct Möbius aromaticity.

AB - β-Tetraphenyl meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin 3 is conformationally flexible between rectangular and figure-of-eight shapes and its two-electron reduced [28]hexaphyrin 4 takes figure-of-eight conformations, which are changed, upon protonation, to twisted conformations with distinct Möbius aromaticity.

UR - http://www.scopus.com/inward/record.url?scp=77949410345&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77949410345&partnerID=8YFLogxK

U2 - 10.1039/b910167e

DO - 10.1039/b910167e

M3 - Article

SP - 6047

EP - 6049

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 40

ER -