Multiple conformational changes of β-tetraphenyl meso- hexakis(pentafluorophenyl) substituted [26] and [28]hexaphyrins(1.1.1.1.1.1)

Taro Koide; Katsuyuki Youfu; Shohei Saito; Atsuhiro Osuka

doi:10.1039/b910167e

Multiple conformational changes of β-tetraphenyl meso- hexakis(pentafluorophenyl) substituted [26] and [28]hexaphyrins(1.1.1.1.1.1)

Taro Koide, Katsuyuki Youfu, Shohei Saito, Atsuhiro Osuka

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

β-Tetraphenyl meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin 3 is conformationally flexible between rectangular and figure-of-eight shapes and its two-electron reduced [28]hexaphyrin 4 takes figure-of-eight conformations, which are changed, upon protonation, to twisted conformations with distinct Möbius aromaticity.

Original language	English
Pages (from-to)	6047-6049
Number of pages	3
Journal	Chemical Communications
Issue number	40
DOIs	https://doi.org/10.1039/b910167e
Publication status	Published - 2009
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b910167e

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abstract = "β-Tetraphenyl meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin 3 is conformationally flexible between rectangular and figure-of-eight shapes and its two-electron reduced [28]hexaphyrin 4 takes figure-of-eight conformations, which are changed, upon protonation, to twisted conformations with distinct M{\"o}bius aromaticity.",

author = "Taro Koide and Katsuyuki Youfu and Shohei Saito and Atsuhiro Osuka",

year = "2009",

doi = "10.1039/b910167e",

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T1 - Multiple conformational changes of β-tetraphenyl meso- hexakis(pentafluorophenyl) substituted [26] and [28]hexaphyrins(1.1.1.1.1.1)

AU - Koide, Taro

AU - Youfu, Katsuyuki

AU - Saito, Shohei

AU - Osuka, Atsuhiro

PY - 2009

Y1 - 2009

N2 - β-Tetraphenyl meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin 3 is conformationally flexible between rectangular and figure-of-eight shapes and its two-electron reduced [28]hexaphyrin 4 takes figure-of-eight conformations, which are changed, upon protonation, to twisted conformations with distinct Möbius aromaticity.

AB - β-Tetraphenyl meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin 3 is conformationally flexible between rectangular and figure-of-eight shapes and its two-electron reduced [28]hexaphyrin 4 takes figure-of-eight conformations, which are changed, upon protonation, to twisted conformations with distinct Möbius aromaticity.

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U2 - 10.1039/b910167e

DO - 10.1039/b910167e

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Multiple conformational changes of β-tetraphenyl meso- hexakis(pentafluorophenyl) substituted [26] and [28]hexaphyrins(1.1.1.1.1.1)

Abstract

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