N-confused and N-fused meso-aryl sapphyrins

Iti Gupta, Alagar Srinivasan, Tatsuki Morimoto, Motoki Toganoh, Hiroyuki Furuta

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

(Chemical Presented) A state of (con)fusion: The introduction of a confused pyrrole ring into a meso-aryl sapphyrin framework destabilizes the macrocycle and forces a fusion reaction to occur. Subsequent metalation with rhenium results in further mutation to form a domino-fused sapphyrin with a fused penta-ring system (see scheme).

Original languageEnglish
Pages (from-to)4563-4567
Number of pages5
JournalAngewandte Chemie - International Edition
Volume47
Issue number24
DOIs
Publication statusPublished - Jun 2 2008

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Fusion reactions
Rhenium
Pyrroles
sapphyrin

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

N-confused and N-fused meso-aryl sapphyrins. / Gupta, Iti; Srinivasan, Alagar; Morimoto, Tatsuki; Toganoh, Motoki; Furuta, Hiroyuki.

In: Angewandte Chemie - International Edition, Vol. 47, No. 24, 02.06.2008, p. 4563-4567.

Research output: Contribution to journalArticle

Gupta, Iti ; Srinivasan, Alagar ; Morimoto, Tatsuki ; Toganoh, Motoki ; Furuta, Hiroyuki. / N-confused and N-fused meso-aryl sapphyrins. In: Angewandte Chemie - International Edition. 2008 ; Vol. 47, No. 24. pp. 4563-4567.
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