N-confused and N-fused meso-aryl sapphyrins

Iti Gupta, Alagar Srinivasan, Tatsuki Morimoto, Motoki Toganoh, Hiroyuki Furuta

    Research output: Contribution to journalArticlepeer-review

    56 Citations (Scopus)

    Abstract

    (Chemical Presented) A state of (con)fusion: The introduction of a confused pyrrole ring into a meso-aryl sapphyrin framework destabilizes the macrocycle and forces a fusion reaction to occur. Subsequent metalation with rhenium results in further mutation to form a domino-fused sapphyrin with a fused penta-ring system (see scheme).

    Original languageEnglish
    Pages (from-to)4563-4567
    Number of pages5
    JournalAngewandte Chemie - International Edition
    Volume47
    Issue number24
    DOIs
    Publication statusPublished - Jun 2 2008

    All Science Journal Classification (ASJC) codes

    • Catalysis
    • Chemistry(all)

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