N-confused and N-fused meso-aryl sapphyrins

Iti Gupta; Alagar Srinivasan; Tatsuki Morimoto; Motoki Toganoh; Hiroyuki Furuta

doi:10.1002/anie.200705984

N-confused and N-fused meso-aryl sapphyrins

Iti Gupta, Alagar Srinivasan, Tatsuki Morimoto, Motoki Toganoh, Hiroyuki Furuta

Applied Fine Chemistry

Research output: Contribution to journal › Article › peer-review

53 Citations (Scopus)

Abstract

(Chemical Presented) A state of (con)fusion: The introduction of a confused pyrrole ring into a meso-aryl sapphyrin framework destabilizes the macrocycle and forces a fusion reaction to occur. Subsequent metalation with rhenium results in further mutation to form a domino-fused sapphyrin with a fused penta-ring system (see scheme).

Original language	English
Pages (from-to)	4563-4567
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	24
DOIs	https://doi.org/10.1002/anie.200705984
Publication status	Published - Jun 2 2008

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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AU - Furuta, Hiroyuki

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N-confused and N-fused meso-aryl sapphyrins

Abstract

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