N-confused and N-fused meso-aryl sapphyrins

Iti Gupta, Alagar Srinivasan, Tatsuki Morimoto, Motoki Toganoh, Hiroyuki Furuta

Research output: Contribution to journalArticle

49 Citations (Scopus)

Abstract

(Chemical Presented) A state of (con)fusion: The introduction of a confused pyrrole ring into a meso-aryl sapphyrin framework destabilizes the macrocycle and forces a fusion reaction to occur. Subsequent metalation with rhenium results in further mutation to form a domino-fused sapphyrin with a fused penta-ring system (see scheme).

Original languageEnglish
Pages (from-to)4563-4567
Number of pages5
JournalAngewandte Chemie - International Edition
Volume47
Issue number24
DOIs
Publication statusPublished - Jun 2 2008

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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