N -confused phlorin: A stable dihydroporphyrin isomer containing a confused pyrrole ring

Masatoshi Ishida, Kensuke Nakahara, Ryuichi Sakashita, Tomoya Ishizuka, Motonori Watanabe, Hidemitsu Uno, Atsuhiro Osuka, Hiroyuki Furuta

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Synthesis of bona fideN-confused phlorin derivatives through simple chemical reduction of N-confused porphyrin precursors using sodium borohydride, p-toluenesulfonyl hydrazide, etc. is described. Spectroscopic, X-ray diffraction analyses and DFT-assisted calculations of these species support the nonaromatic phlorin electronic structure.

Original languageEnglish
Pages (from-to)909-918
Number of pages10
JournalJournal of Porphyrins and Phthalocyanines
Volume18
Issue number10-11
DOIs
Publication statusPublished - May 19 2014

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Pyrroles
Porphyrins
Discrete Fourier transforms
Isomers
Electronic structure
Derivatives
X ray diffraction
4-toluenesulfonyl hydrazide
sodium borohydride

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

N -confused phlorin : A stable dihydroporphyrin isomer containing a confused pyrrole ring. / Ishida, Masatoshi; Nakahara, Kensuke; Sakashita, Ryuichi; Ishizuka, Tomoya; Watanabe, Motonori; Uno, Hidemitsu; Osuka, Atsuhiro; Furuta, Hiroyuki.

In: Journal of Porphyrins and Phthalocyanines, Vol. 18, No. 10-11, 19.05.2014, p. 909-918.

Research output: Contribution to journalArticle

Ishida, Masatoshi ; Nakahara, Kensuke ; Sakashita, Ryuichi ; Ishizuka, Tomoya ; Watanabe, Motonori ; Uno, Hidemitsu ; Osuka, Atsuhiro ; Furuta, Hiroyuki. / N -confused phlorin : A stable dihydroporphyrin isomer containing a confused pyrrole ring. In: Journal of Porphyrins and Phthalocyanines. 2014 ; Vol. 18, No. 10-11. pp. 909-918.
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