Abstract
A skeleton of N-confused porphyrin (NC-porphine) has been synthesized for the first time, through a [3+1] coupling reaction. A completely planar inner 3H tautomeric form was found in the crystals, and the molecular packing shows a sandwich herringbone structure similar to that of normal porphine, whilst some of the spectroscopic properties demonstrate systematic substituent effects by the meso-phenyl groups on the N-confused porphyrin.
Original language | English |
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Pages (from-to) | 3887-3890 |
Number of pages | 4 |
Journal | European Journal of Organic Chemistry |
Issue number | 18 |
DOIs | |
Publication status | Published - Sept 12 2005 |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
- Organic Chemistry