N-confused porphyrin-bearing meso-perfluorophenyl groups: A potential agent that forms stable square-planar complexes with Cu(II) and Ag(III)

Hiromitsu Maeda, Atsuhiro Osuka, Yuichi Ishikawa, Isao Aritome, Yoshio Hisaeda, Hiroyuki Furuta

Research output: Contribution to journalArticlepeer-review

95 Citations (Scopus)

Abstract

(Matrix presented) N-Confused porphyrin (NCP) bearing pentafluorophenyl groups at meso-positions, which were obtained from N-confused dipyrromethane in ca. 20% yield, can form Cu(II) complex as well as Ag(III), Ni(II), and Pd(II) complexes. The square-planar structures of all these metal complexes were elucidated by X-ray single-crystal analyses.

Original languageEnglish
Pages (from-to)1293-1296
Number of pages4
JournalOrganic Letters
Volume5
Issue number8
DOIs
Publication statusPublished - Apr 17 2003

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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