N-confused porphyrin-bearing meso-perfluorophenyl groups: A potential agent that forms stable square-planar complexes with Cu(II) and Ag(III)

Hiromitsu Maeda, Atsuhiro Osuka, Yuichi Ishikawa, Isao Aritome, Yoshio Hisaeda, Hiroyuki Furuta

Research output: Contribution to journalArticle

90 Citations (Scopus)

Abstract

(Matrix presented) N-Confused porphyrin (NCP) bearing pentafluorophenyl groups at meso-positions, which were obtained from N-confused dipyrromethane in ca. 20% yield, can form Cu(II) complex as well as Ag(III), Ni(II), and Pd(II) complexes. The square-planar structures of all these metal complexes were elucidated by X-ray single-crystal analyses.

Original languageEnglish
Pages (from-to)1293-1296
Number of pages4
JournalOrganic Letters
Volume5
Issue number8
DOIs
Publication statusPublished - Apr 17 2003

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Bearings (structural)
Coordination Complexes
planar structures
Porphyrins
porphyrins
X-Rays
Single crystals
X rays
single crystals
matrices
metals
x rays
dipyrromethane

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

N-confused porphyrin-bearing meso-perfluorophenyl groups : A potential agent that forms stable square-planar complexes with Cu(II) and Ag(III). / Maeda, Hiromitsu; Osuka, Atsuhiro; Ishikawa, Yuichi; Aritome, Isao; Hisaeda, Yoshio; Furuta, Hiroyuki.

In: Organic Letters, Vol. 5, No. 8, 17.04.2003, p. 1293-1296.

Research output: Contribution to journalArticle

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AU - Furuta, Hiroyuki

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