N-Confused Porphyrin Metal Complexes with an Axial Pyridine Directly Tethered from an Inner Carbon: A Bioinspired Ligand as a Versatile Platform for Catalysis

Takaaki Miyazaki, Takaaki Yamamoto, Shunichi Mashita, Yuya Deguchi, Kazuki Fukuyama, Masatoshi Ishida, Shigeki Mori, Hiroyuki Furuta

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Bioinspired pentadentate ligand N-confused porphyrin (NCP) bearing a 2-mercaptopyridine group and its RuII and CoIII complexes were synthesized. Their structures were revealed by single-crystal X-ray crystallographic analysis. Installation of an axial thiopyridine ligand shifts the redox potentials negatively and enhances the catalytic activity largely, which was demonstrated in the cyclopropanation reaction using the Co complex.

Original languageEnglish
Pages (from-to)203-207
Number of pages5
JournalEuropean Journal of Inorganic Chemistry
Volume2018
Issue number2
DOIs
Publication statusPublished - Jan 23 2018

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Coordination Complexes
Porphyrins
Catalysis
Bearings (structural)
Carbon
Ligands
Catalyst activity
Single crystals
X rays
pyridine
Oxidation-Reduction
2-thiopyridine

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

N-Confused Porphyrin Metal Complexes with an Axial Pyridine Directly Tethered from an Inner Carbon : A Bioinspired Ligand as a Versatile Platform for Catalysis. / Miyazaki, Takaaki; Yamamoto, Takaaki; Mashita, Shunichi; Deguchi, Yuya; Fukuyama, Kazuki; Ishida, Masatoshi; Mori, Shigeki; Furuta, Hiroyuki.

In: European Journal of Inorganic Chemistry, Vol. 2018, No. 2, 23.01.2018, p. 203-207.

Research output: Contribution to journalArticle

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