TY - JOUR
T1 - N-confused porphyrins as new scaffolds for supramolecular architecture
AU - Maeda, Hiromitsu
AU - Furuta, Hiroyuki
PY - 2004
Y1 - 2004
N2 - The peripheral nitrogen of N-confused porphyrins (NCP) can serve as a hydrogen bonding donor and acceptor, and a metal coordination site as well. NCP forms versatile dimers with the assistance of metal ions such as Pd II, PtII, ZnII, CdII, Hg II, MnII and FeII. The square-planar divalent metal complexes of C6F6-substituted NCP with Cu II, NiII and PdII act as efficient anion binding receptors. The doubly N-confused porphyrins (N2CP), possessing both N and NH at the periphery, form self-assembled 1-D hydrogen bonding networks, whose orientations differ in cis (zigzag) and trans (straight) isomers.
AB - The peripheral nitrogen of N-confused porphyrins (NCP) can serve as a hydrogen bonding donor and acceptor, and a metal coordination site as well. NCP forms versatile dimers with the assistance of metal ions such as Pd II, PtII, ZnII, CdII, Hg II, MnII and FeII. The square-planar divalent metal complexes of C6F6-substituted NCP with Cu II, NiII and PdII act as efficient anion binding receptors. The doubly N-confused porphyrins (N2CP), possessing both N and NH at the periphery, form self-assembled 1-D hydrogen bonding networks, whose orientations differ in cis (zigzag) and trans (straight) isomers.
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U2 - 10.1142/s1088424604000052
DO - 10.1142/s1088424604000052
M3 - Review article
AN - SCOPUS:3342971297
SN - 1088-4246
VL - 8
SP - 67
EP - 75
JO - Journal of Porphyrins and Phthalocyanines
JF - Journal of Porphyrins and Phthalocyanines
IS - 1-3
ER -