(N-Methyl-4,4′-bipyridinium)(2,2′:6′,2″- terpyridine)platinum(II) triperchlorate monohydrate

Ken Sakai, Mai Kurashima, Manabu Osada, Satoru Takahashi

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

In the title compound, [Pt(C15H11N 3)(C11H11N2)](ClO4) 3-H2O, the PtN4 coordination plane is distorted from a planar geometry owing to the relatively strong intermolecular terpy-terpy interactions, giving rise to a bent structure with respect to the terpy moiety (terpy = 2,2′:6′,2″-terpyridine). The coordinated pyridyl plane of N-methyl-4,4′-bipyridinium (MQ) is inclined by 81.7 (1)° with respect to the Pt coordination plane. The dihedral angle between the two pyridyl planes within MQ is 33.5 (2)°.

Original languageEnglish
Pages (from-to)m515-m517
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number7
DOIs
Publication statusPublished - Jul 1 2003

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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