(N-Methyl-4,4′-bipyridinium)(2,2′:6′,2″- terpyridine)platinum(II) triperchlorate monohydrate

Ken Sakai; Mai Kurashima; Manabu Osada; Satoru Takahashi

doi:10.1107/S1600536803013837

(N-Methyl-4,4′-bipyridinium)(2,2′:6′,2″- terpyridine)platinum(II) triperchlorate monohydrate

Ken Sakai, Mai Kurashima, Manabu Osada, Satoru Takahashi

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

In the title compound, [Pt(C₁₅H₁₁N ₃)(C₁₁H₁₁N₂)](ClO₄) ₃-H₂O, the PtN₄ coordination plane is distorted from a planar geometry owing to the relatively strong intermolecular terpy-terpy interactions, giving rise to a bent structure with respect to the terpy moiety (terpy = 2,2′:6′,2″-terpyridine). The coordinated pyridyl plane of N-methyl-4,4′-bipyridinium (MQ) is inclined by 81.7 (1)° with respect to the Pt coordination plane. The dihedral angle between the two pyridyl planes within MQ is 33.5 (2)°.

Original language	English
Pages (from-to)	m515-m517
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	7
DOIs	https://doi.org/10.1107/S1600536803013837
Publication status	Published - Jul 1 2003
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1107/S1600536803013837

Cite this

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title = "(N-Methyl-4,4′-bipyridinium)(2,2′:6′,2″- terpyridine)platinum(II) triperchlorate monohydrate",

abstract = "In the title compound, [Pt(C15H11N 3)(C11H11N2)](ClO4) 3-H2O, the PtN4 coordination plane is distorted from a planar geometry owing to the relatively strong intermolecular terpy-terpy interactions, giving rise to a bent structure with respect to the terpy moiety (terpy = 2,2′:6′,2″-terpyridine). The coordinated pyridyl plane of N-methyl-4,4′-bipyridinium (MQ) is inclined by 81.7 (1)° with respect to the Pt coordination plane. The dihedral angle between the two pyridyl planes within MQ is 33.5 (2)°.",

author = "Ken Sakai and Mai Kurashima and Manabu Osada and Satoru Takahashi",

year = "2003",

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doi = "10.1107/S1600536803013837",

language = "English",

volume = "59",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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T1 - (N-Methyl-4,4′-bipyridinium)(2,2′:6′,2″- terpyridine)platinum(II) triperchlorate monohydrate

AU - Sakai, Ken

AU - Kurashima, Mai

AU - Osada, Manabu

AU - Takahashi, Satoru

PY - 2003/7/1

Y1 - 2003/7/1

N2 - In the title compound, [Pt(C15H11N 3)(C11H11N2)](ClO4) 3-H2O, the PtN4 coordination plane is distorted from a planar geometry owing to the relatively strong intermolecular terpy-terpy interactions, giving rise to a bent structure with respect to the terpy moiety (terpy = 2,2′:6′,2″-terpyridine). The coordinated pyridyl plane of N-methyl-4,4′-bipyridinium (MQ) is inclined by 81.7 (1)° with respect to the Pt coordination plane. The dihedral angle between the two pyridyl planes within MQ is 33.5 (2)°.

AB - In the title compound, [Pt(C15H11N 3)(C11H11N2)](ClO4) 3-H2O, the PtN4 coordination plane is distorted from a planar geometry owing to the relatively strong intermolecular terpy-terpy interactions, giving rise to a bent structure with respect to the terpy moiety (terpy = 2,2′:6′,2″-terpyridine). The coordinated pyridyl plane of N-methyl-4,4′-bipyridinium (MQ) is inclined by 81.7 (1)° with respect to the Pt coordination plane. The dihedral angle between the two pyridyl planes within MQ is 33.5 (2)°.

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(N-Methyl-4,4′-bipyridinium)(2,2′:6′,2″- terpyridine)platinum(II) triperchlorate monohydrate

Abstract

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