Nanocellulose–surfactant interactions

Blaise L. Tardy, Shingo Yokota, Mariko Ago, Wenchao Xiang, Tetsuo Kondo, Romain Bordes, Orlando J. Rojas

Research output: Contribution to journalReview article

36 Citations (Scopus)

Abstract

Biomass-derived nanomaterials, such as cellulose nanocrystals and nanofibrils, are attractive building blocks for the formulation of foams, emulsions, suspensions and multiphase systems. Depending on their surface chemistry, aspect ratio and crystallinity, nanocelluloses can control the rheology and stability of dispersions; they can also confer robust mechanical properties to composites. Synthetic modification of fibrillar cellulose is an option to achieve chemical compatibility in related systems, in the formation of composites, etc. However, this can also limit the environmental benefits gained from the use of the cellulosic component. Thus, an attractive mean to compatibilize and to further expand the applications of nanocelluloses is through the use of surfactants. The chemical toolbox of surfactants developed over the last 60 years allows for a large versatility while their environmental impact can also be minimized. Furthermore, relatively small amounts of surfactants are sufficient to significantly impact the interfacial forces, which has implications in material development, from the colloidal scale to the macro-scale. In this review we attempt to cover the literature pertaining to the combined uses of surfactants and nanocelluloses. We summarize reports on the incorporation with nanocellulose of nonionic, anionic, amphoteric and cationic surfactants. With the ever-expanding interest in the use of renewable materials in a vast range of applications, we hope to provide insights into the application of surfactants as a tool to tailor the compatibility and the surface chemistry of nanocelluloses.

Original languageEnglish
Pages (from-to)57-67
Number of pages11
JournalCurrent Opinion in Colloid and Interface Science
Volume29
DOIs
Publication statusPublished - May 1 2017

Fingerprint

Beam plasma interactions
Surface-Active Agents
Surface active agents
surfactants
Surface chemistry
Cellulose
interactions
cellulose
Amphoteric surfactants
chemical compatibility
chemistry
Anionic surfactants
Cationic surfactants
Nonionic surfactants
Composite materials
Emulsions
Dispersions
Rheology
composite materials
Nanostructured materials

All Science Journal Classification (ASJC) codes

  • Surfaces and Interfaces
  • Physical and Theoretical Chemistry
  • Polymers and Plastics
  • Colloid and Surface Chemistry

Cite this

Nanocellulose–surfactant interactions. / Tardy, Blaise L.; Yokota, Shingo; Ago, Mariko; Xiang, Wenchao; Kondo, Tetsuo; Bordes, Romain; Rojas, Orlando J.

In: Current Opinion in Colloid and Interface Science, Vol. 29, 01.05.2017, p. 57-67.

Research output: Contribution to journalReview article

Tardy, Blaise L. ; Yokota, Shingo ; Ago, Mariko ; Xiang, Wenchao ; Kondo, Tetsuo ; Bordes, Romain ; Rojas, Orlando J. / Nanocellulose–surfactant interactions. In: Current Opinion in Colloid and Interface Science. 2017 ; Vol. 29. pp. 57-67.
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