TY - JOUR
T1 - Nanosheet-like Lithium Borohydride Hydrate with 10 wt % Hydrogen Release at 70 °c as a Chemical Hydrogen Storage Candidate
AU - Wu, Ruyan
AU - Ren, Zhuanghe
AU - Zhang, Xin
AU - Lu, Yunhao
AU - Li, Haiwen
AU - Gao, Mingxia
AU - Pan, Hongge
AU - Liu, Yongfeng
N1 - Funding Information:
We gratefully acknowledge the financial support received from the National Key R&D Program of China (2018YFB1502102), the National Natural Science Foundation of China (51671172, U1601212), and the National Youth Top-Notch Talent Support Program.
Publisher Copyright:
Copyright © 2019 American Chemical Society.
PY - 2019/4/18
Y1 - 2019/4/18
N2 - A nanosheet-like lithium borohydride hydrate (LiBH 4 ·H 2 O) measuring 20-30 nm in thickness is successfully synthesized for the first time by a facile, scalable freeze-drying strategy. The prepared LiBH 4 ·H 2 O nanosheets start releasing hydrogen below 50 °C and release an amount up to approximately 10 wt % at 70 °C because of the strong affinity of H + in the H 2 O ligand and H - in the BH 4 group. The reported dehydrogenation properties here are superior to those of all known complex hydrides, indicating applicability as an advanced chemical hydrogen storage medium.
AB - A nanosheet-like lithium borohydride hydrate (LiBH 4 ·H 2 O) measuring 20-30 nm in thickness is successfully synthesized for the first time by a facile, scalable freeze-drying strategy. The prepared LiBH 4 ·H 2 O nanosheets start releasing hydrogen below 50 °C and release an amount up to approximately 10 wt % at 70 °C because of the strong affinity of H + in the H 2 O ligand and H - in the BH 4 group. The reported dehydrogenation properties here are superior to those of all known complex hydrides, indicating applicability as an advanced chemical hydrogen storage medium.
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U2 - 10.1021/acs.jpclett.9b00416
DO - 10.1021/acs.jpclett.9b00416
M3 - Article
C2 - 30880396
AN - SCOPUS:85064342760
SN - 1948-7185
VL - 10
SP - 1872
EP - 1877
JO - Journal of Physical Chemistry Letters
JF - Journal of Physical Chemistry Letters
IS - 8
ER -