Conductivity of La1.61GeO5-δ thin films increased with decreasing film thickness to nanosize or several micrometers. In particular, the evaluation of the conductivity for the films with nanosize thickness at low temperatures was significant. The conductivity of the film was independent of the oxygen partial pressure from 1 to 10-21 atm and the transport number of oxygen ion in the film was near unity, suggesting that the oxygen ionic conductivity was dominant over a wide pO2 range. This effect was induced by the large anisotropy of the oxide ionic conduction and the expansion of the lattice of La1.61GeO5-δ.
|Journal||Electrochemical and Solid-State Letters|
|Publication status||Published - Nov 21 2005|
All Science Journal Classification (ASJC) codes
- Chemical Engineering(all)
- Materials Science(all)
- Physical and Theoretical Chemistry
- Electrical and Electronic Engineering