Nanostructural characterization and catalytic analysis of hybridized platinumphthalocyanine nanocomposites

Kenji Kaneko; Kazuki Furuya; Ana B. Hungria; Juan Carlos Hernandez-Garrido; Paul A. Midgley; Tsunenobu Onodera; Hitoshi Kasai; Yusuke Yaguchi; Hidetoshi Oikawa; Yohei Nomura; Hiroki Harada; Tatsumi Ishihara; Norio Baba

doi:10.1093/jmicro/dfp027

Nanostructural characterization and catalytic analysis of hybridized platinumphthalocyanine nanocomposites

Kenji Kaneko, Kazuki Furuya, Ana B. Hungria, Juan Carlos Hernandez-Garrido, Paul A. Midgley, Tsunenobu Onodera, Hitoshi Kasai, Yusuke Yaguchi, Hidetoshi Oikawa, Yohei Nomura, Hiroki Harada, Tatsumi Ishihara, Norio Baba

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6 Citations (Scopus)

Abstract

Organic crystals, such as phthalocyanine nanocrystal, were successfully hybridized with Pt nanoparticles using a nanohybridization technique. The presence of highly dispersed Pt nanoparticles on the surface of phthalocyanine was confirmed by the combination of transmission electron microscopy and three-dimensional electron tomography. Catalytic activities of hybridized samples with different degrees of dispersions were also examined as oxygen reduction reactivity (ORR) with a linear potential sweep method. It was found that oxygen reduction activity increased with increasing Pt dispersion, and reasonably high ORR was observed on Pt-dispersed phthalocyanine nanocrystal even at 2 wt Pt loading.

Original language	English
Pages (from-to)	289-294
Number of pages	6
Journal	Journal of Electron Microscopy
Volume	58
Issue number	5
DOIs	https://doi.org/10.1093/jmicro/dfp027
Publication status	Published - Oct 2009

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Kaneko, K., Furuya, K., Hungria, A. B., Hernandez-Garrido, J. C., Midgley, P. A., Onodera, T., Kasai, H., Yaguchi, Y., Oikawa, H., Nomura, Y., Harada, H., Ishihara, T., & Baba, N. (2009). Nanostructural characterization and catalytic analysis of hybridized platinumphthalocyanine nanocomposites. Journal of Electron Microscopy, 58(5), 289-294. https://doi.org/10.1093/jmicro/dfp027

Kaneko, K, Furuya, K, Hungria, AB, Hernandez-Garrido, JC, Midgley, PA, Onodera, T, Kasai, H, Yaguchi, Y, Oikawa, H, Nomura, Y, Harada, H, Ishihara, T & Baba, N 2009, 'Nanostructural characterization and catalytic analysis of hybridized platinumphthalocyanine nanocomposites', Journal of Electron Microscopy, vol. 58, no. 5, pp. 289-294. https://doi.org/10.1093/jmicro/dfp027

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title = "Nanostructural characterization and catalytic analysis of hybridized platinumphthalocyanine nanocomposites",

abstract = "Organic crystals, such as phthalocyanine nanocrystal, were successfully hybridized with Pt nanoparticles using a nanohybridization technique. The presence of highly dispersed Pt nanoparticles on the surface of phthalocyanine was confirmed by the combination of transmission electron microscopy and three-dimensional electron tomography. Catalytic activities of hybridized samples with different degrees of dispersions were also examined as oxygen reduction reactivity (ORR) with a linear potential sweep method. It was found that oxygen reduction activity increased with increasing Pt dispersion, and reasonably high ORR was observed on Pt-dispersed phthalocyanine nanocrystal even at 2 wt Pt loading.",

author = "Kenji Kaneko and Kazuki Furuya and Hungria, {Ana B.} and Hernandez-Garrido, {Juan Carlos} and Midgley, {Paul A.} and Tsunenobu Onodera and Hitoshi Kasai and Yusuke Yaguchi and Hidetoshi Oikawa and Yohei Nomura and Hiroki Harada and Tatsumi Ishihara and Norio Baba",

note = "Funding Information: This work was supported in part by {\textquoteleft}grant-in-aid for the Global COE Program (Functional Innovation of Molecular Informatics){\textquoteright} and {\textquoteleft}grant-in-aid for Scientific Research (no. 19360317){\textquoteright} from the Japan Society for the Promotion of Science (JSPS) and by JST, CREST. P.A.M. thanks the Isaac Newton Trust for funding and the Royal Academy of Engineering and the Leverhulme Trust for the award of Senior Research Fellowships. A.B.H. thanks the European Community for a Marie Curie Research Fellowship. J.C.H thanks the European Union for financial support under the Frame-work 6 program for an Integrated Infrastructure Initiative, ref.: 026019 ESTEEM. Copyright: Copyright 2013 Elsevier B.V., All rights reserved.",

year = "2009",

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doi = "10.1093/jmicro/dfp027",

language = "English",

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AU - Kaneko, Kenji

AU - Furuya, Kazuki

AU - Hungria, Ana B.

AU - Hernandez-Garrido, Juan Carlos

AU - Midgley, Paul A.

AU - Onodera, Tsunenobu

AU - Kasai, Hitoshi

AU - Yaguchi, Yusuke

AU - Oikawa, Hidetoshi

AU - Nomura, Yohei

AU - Harada, Hiroki

AU - Ishihara, Tatsumi

AU - Baba, Norio

N1 - Funding Information: This work was supported in part by ‘grant-in-aid for the Global COE Program (Functional Innovation of Molecular Informatics)’ and ‘grant-in-aid for Scientific Research (no. 19360317)’ from the Japan Society for the Promotion of Science (JSPS) and by JST, CREST. P.A.M. thanks the Isaac Newton Trust for funding and the Royal Academy of Engineering and the Leverhulme Trust for the award of Senior Research Fellowships. A.B.H. thanks the European Community for a Marie Curie Research Fellowship. J.C.H thanks the European Union for financial support under the Frame-work 6 program for an Integrated Infrastructure Initiative, ref.: 026019 ESTEEM. Copyright: Copyright 2013 Elsevier B.V., All rights reserved.

PY - 2009/10

Y1 - 2009/10

N2 - Organic crystals, such as phthalocyanine nanocrystal, were successfully hybridized with Pt nanoparticles using a nanohybridization technique. The presence of highly dispersed Pt nanoparticles on the surface of phthalocyanine was confirmed by the combination of transmission electron microscopy and three-dimensional electron tomography. Catalytic activities of hybridized samples with different degrees of dispersions were also examined as oxygen reduction reactivity (ORR) with a linear potential sweep method. It was found that oxygen reduction activity increased with increasing Pt dispersion, and reasonably high ORR was observed on Pt-dispersed phthalocyanine nanocrystal even at 2 wt Pt loading.

AB - Organic crystals, such as phthalocyanine nanocrystal, were successfully hybridized with Pt nanoparticles using a nanohybridization technique. The presence of highly dispersed Pt nanoparticles on the surface of phthalocyanine was confirmed by the combination of transmission electron microscopy and three-dimensional electron tomography. Catalytic activities of hybridized samples with different degrees of dispersions were also examined as oxygen reduction reactivity (ORR) with a linear potential sweep method. It was found that oxygen reduction activity increased with increasing Pt dispersion, and reasonably high ORR was observed on Pt-dispersed phthalocyanine nanocrystal even at 2 wt Pt loading.

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Nanostructural characterization and catalytic analysis of hybridized platinumphthalocyanine nanocomposites

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