Abstract
A series of conductive porous composites were obtained by the polymerization of 3,4-ethylenedioxythiophene (EDOT) in the cavities of MIL-101(Cr). By controlling the amount of EDOT loaded into the host framework, it was possible to modulate the conductivity as well as the porosity of the composite. This approach yields materials with a reasonable electronic conductivity (1.1 × 10-3 S·cm-1) while maintaining high porosity (SBET = 803 m2/g). This serves as a promising strategy for obtaining highly nanotextured conductive polymers with very high accessibility for small gas molecules, which are beneficial to the fabrication of a chemiresistive sensor for the detection of NO2.
| Original language | English |
|---|---|
| Pages (from-to) | 10088-10091 |
| Number of pages | 4 |
| Journal | Journal of the American Chemical Society |
| Volume | 138 |
| Issue number | 32 |
| DOIs | |
| Publication status | Published - Aug 17 2016 |
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All Science Journal Classification (ASJC) codes
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
Cite this
Nanostructuration of PEDOT in Porous Coordination Polymers for Tunable Porosity and Conductivity. / Le Ouay, Benjamin; Boudot, Mickael; Kitao, Takashi; Yanagida, Takeshi; Kitagawa, Susumu; Uemura, Takashi.
In: Journal of the American Chemical Society, Vol. 138, No. 32, 17.08.2016, p. 10088-10091.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Nanostructuration of PEDOT in Porous Coordination Polymers for Tunable Porosity and Conductivity
AU - Le Ouay, Benjamin
AU - Boudot, Mickael
AU - Kitao, Takashi
AU - Yanagida, Takeshi
AU - Kitagawa, Susumu
AU - Uemura, Takashi
PY - 2016/8/17
Y1 - 2016/8/17
N2 - A series of conductive porous composites were obtained by the polymerization of 3,4-ethylenedioxythiophene (EDOT) in the cavities of MIL-101(Cr). By controlling the amount of EDOT loaded into the host framework, it was possible to modulate the conductivity as well as the porosity of the composite. This approach yields materials with a reasonable electronic conductivity (1.1 × 10-3 S·cm-1) while maintaining high porosity (SBET = 803 m2/g). This serves as a promising strategy for obtaining highly nanotextured conductive polymers with very high accessibility for small gas molecules, which are beneficial to the fabrication of a chemiresistive sensor for the detection of NO2.
AB - A series of conductive porous composites were obtained by the polymerization of 3,4-ethylenedioxythiophene (EDOT) in the cavities of MIL-101(Cr). By controlling the amount of EDOT loaded into the host framework, it was possible to modulate the conductivity as well as the porosity of the composite. This approach yields materials with a reasonable electronic conductivity (1.1 × 10-3 S·cm-1) while maintaining high porosity (SBET = 803 m2/g). This serves as a promising strategy for obtaining highly nanotextured conductive polymers with very high accessibility for small gas molecules, which are beneficial to the fabrication of a chemiresistive sensor for the detection of NO2.
UR - http://www.scopus.com/inward/record.url?scp=84983616187&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84983616187&partnerID=8YFLogxK
U2 - 10.1021/jacs.6b05552
DO - 10.1021/jacs.6b05552
M3 - Article
AN - SCOPUS:84983616187
VL - 138
SP - 10088
EP - 10091
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 32
ER -