TY - JOUR
T1 - Nanostructuration of PEDOT in Porous Coordination Polymers for Tunable Porosity and Conductivity
AU - Le Ouay, Benjamin
AU - Boudot, Mickael
AU - Kitao, Takashi
AU - Yanagida, Takeshi
AU - Kitagawa, Susumu
AU - Uemura, Takashi
N1 - Funding Information:
This work was supported by the JST, CREST program, and a Grant-in Aid for Science Research on Innovative Area New Polymeric Materials Based on Element-Blocks (No. 2401) from the Ministry of Education, Culture, Sports, Science and Technology, Government of Japan.
Publisher Copyright:
© 2016 American Chemical Society.
PY - 2016/8/17
Y1 - 2016/8/17
N2 - A series of conductive porous composites were obtained by the polymerization of 3,4-ethylenedioxythiophene (EDOT) in the cavities of MIL-101(Cr). By controlling the amount of EDOT loaded into the host framework, it was possible to modulate the conductivity as well as the porosity of the composite. This approach yields materials with a reasonable electronic conductivity (1.1 × 10-3 S·cm-1) while maintaining high porosity (SBET = 803 m2/g). This serves as a promising strategy for obtaining highly nanotextured conductive polymers with very high accessibility for small gas molecules, which are beneficial to the fabrication of a chemiresistive sensor for the detection of NO2.
AB - A series of conductive porous composites were obtained by the polymerization of 3,4-ethylenedioxythiophene (EDOT) in the cavities of MIL-101(Cr). By controlling the amount of EDOT loaded into the host framework, it was possible to modulate the conductivity as well as the porosity of the composite. This approach yields materials with a reasonable electronic conductivity (1.1 × 10-3 S·cm-1) while maintaining high porosity (SBET = 803 m2/g). This serves as a promising strategy for obtaining highly nanotextured conductive polymers with very high accessibility for small gas molecules, which are beneficial to the fabrication of a chemiresistive sensor for the detection of NO2.
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U2 - 10.1021/jacs.6b05552
DO - 10.1021/jacs.6b05552
M3 - Article
AN - SCOPUS:84983616187
VL - 138
SP - 10088
EP - 10091
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 32
ER -