Nanostructure-induced hydrogenation of layered compound MgB2

Haiwen Li, Tomoya Matsunaga, Yigang Yan, Hideki Maekawa, Mamoru Ishikiriyama, Shin Ichi Orimo

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

We investigated the hydrogenation properties of layered compound MgB 2 mechanically milled under a hydrogen pressure of 1.0 MPa. The total hydrogen concentration after milling for 600 min was approximately 1.0 mass%. No hydrogen insertion into MgB2 interlayer was observed from interlayer distance analysis. On the other hand, mechanical milling generated the nanostructured MgB2 with grain boundary defects in which B-H covalent bond and/or Mg-H bond were assumed to be formed. The nanostructure with grain boundary defects significantly promoted the subsequent high pressure (40.0 MPa) hydrogenation of MgB2 for the synthesis of Mg(BH 4)2 comprising [BH4]- anions with B-H covalent bonds.

Original languageEnglish
Pages (from-to)654-656
Number of pages3
JournalJournal of Alloys and Compounds
Volume505
Issue number2
DOIs
Publication statusPublished - Sep 3 2010
Externally publishedYes

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Hydrogenation
Hydrogen
Nanostructures
Covalent bonds
Grain boundaries
Defects
Anions
Negative ions

All Science Journal Classification (ASJC) codes

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

Cite this

Li, H., Matsunaga, T., Yan, Y., Maekawa, H., Ishikiriyama, M., & Orimo, S. I. (2010). Nanostructure-induced hydrogenation of layered compound MgB2 Journal of Alloys and Compounds, 505(2), 654-656. https://doi.org/10.1016/j.jallcom.2010.06.101

Nanostructure-induced hydrogenation of layered compound MgB2 . / Li, Haiwen; Matsunaga, Tomoya; Yan, Yigang; Maekawa, Hideki; Ishikiriyama, Mamoru; Orimo, Shin Ichi.

In: Journal of Alloys and Compounds, Vol. 505, No. 2, 03.09.2010, p. 654-656.

Research output: Contribution to journalArticle

Li, H, Matsunaga, T, Yan, Y, Maekawa, H, Ishikiriyama, M & Orimo, SI 2010, 'Nanostructure-induced hydrogenation of layered compound MgB2 ', Journal of Alloys and Compounds, vol. 505, no. 2, pp. 654-656. https://doi.org/10.1016/j.jallcom.2010.06.101
Li, Haiwen ; Matsunaga, Tomoya ; Yan, Yigang ; Maekawa, Hideki ; Ishikiriyama, Mamoru ; Orimo, Shin Ichi. / Nanostructure-induced hydrogenation of layered compound MgB2 In: Journal of Alloys and Compounds. 2010 ; Vol. 505, No. 2. pp. 654-656.
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