Nature of the singlet and triplet excitations mediating thermally activated delayed fluorescence

Y. Olivier, B. Yurash, L. Muccioli, G. D'Avino, O. Mikhnenko, J. C. Sancho-García, C. Adachi, T. Q. Nguyen, D. Beljonne

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Despite significant efforts, a complete mechanistic understanding of thermally activated delayed fluorescence (TADF) materials has not yet been fully uncovered. Part of the complexity arises from the apparent dichotomy between the need for close energy resonance and for a significant spin-orbit coupling between alike charge-transfer singlet and triplet excitations. Here we show, in the case of reference carbazole derivatives, that this dichotomy can be resolved in a fully atomistic model accounting for thermal fluctuations of the molecular conformations and microscopic electronic polarization effects in amorphous films. These effects yield electronic excitations with a dynamically mixed charge-transfer and localized character, resulting in thermally averaged singlet-triplet energy differences and interconversion rates in excellent agreement with careful spectroscopic studies.

Original languageEnglish
Article number075602
JournalPhysical Review Materials
Volume1
Issue number7
DOIs
Publication statusPublished - Dec 27 2017

Fingerprint

dichotomies
atomic energy levels
Charge transfer
Fluorescence
charge transfer
fluorescence
carbazoles
Amorphous films
electronics
excitation
Conformations
Orbits
Polarization
Derivatives
orbits
energy
polarization
Hot Temperature
carbazole

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Physics and Astronomy (miscellaneous)

Cite this

Olivier, Y., Yurash, B., Muccioli, L., D'Avino, G., Mikhnenko, O., Sancho-García, J. C., ... Beljonne, D. (2017). Nature of the singlet and triplet excitations mediating thermally activated delayed fluorescence. Physical Review Materials, 1(7), [075602]. https://doi.org/10.1103/PhysRevMaterials.1.075602

Nature of the singlet and triplet excitations mediating thermally activated delayed fluorescence. / Olivier, Y.; Yurash, B.; Muccioli, L.; D'Avino, G.; Mikhnenko, O.; Sancho-García, J. C.; Adachi, C.; Nguyen, T. Q.; Beljonne, D.

In: Physical Review Materials, Vol. 1, No. 7, 075602, 27.12.2017.

Research output: Contribution to journalArticle

Olivier, Y, Yurash, B, Muccioli, L, D'Avino, G, Mikhnenko, O, Sancho-García, JC, Adachi, C, Nguyen, TQ & Beljonne, D 2017, 'Nature of the singlet and triplet excitations mediating thermally activated delayed fluorescence', Physical Review Materials, vol. 1, no. 7, 075602. https://doi.org/10.1103/PhysRevMaterials.1.075602
Olivier, Y. ; Yurash, B. ; Muccioli, L. ; D'Avino, G. ; Mikhnenko, O. ; Sancho-García, J. C. ; Adachi, C. ; Nguyen, T. Q. ; Beljonne, D. / Nature of the singlet and triplet excitations mediating thermally activated delayed fluorescence. In: Physical Review Materials. 2017 ; Vol. 1, No. 7.
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