Nb2O5-based composite electrodes for dye-sensitized solar cells

Koichi Eguchi, Hideyuki Koga, Koshi Sekizawa, Kazunari Sasaki

Research output: Contribution to journalArticlepeer-review

32 Citations (Scopus)

Abstract

Various semiconducting oxides are examined as alternative electrode materials for dye-sensitized solar cells. It was confirmed that Nb2O5-based electrodes exhibit a higher open-circuit voltage and fill factor, compared to TiO2-based electrodes. It was also found that a mixing of oxides, with a higher flat-band potential level such as SrTiO3, Ta2O5, and ZrO2, with Nb2O5 led to a higher open-circuit voltage. By mixing Nb2O5 with TiO2 in different ratios, it was revealed that these oxides form no chemical reaction products after a low-temperature heat treatment and a highest power output of the cells with the composite electrodes was obtained at Nb2O5 : TiO2 = 8 : 2 in mass. The power output with this composite electrode was higher than that with pure Nb2O5 or with pure TiO2. The Nb2O5-TiO2 composite electrode, in which the Nb2O5 particles are dispersed on the TiO2 surfaces, exhibits high photoelectrochemical performance.

Original languageEnglish
Pages (from-to)1067-1071
Number of pages5
JournalJournal of the Ceramic Society of Japan
Volume108
Issue number12
DOIs
Publication statusPublished - 2000

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry

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